MALLINCKRODT BAKER INC -- SODIUM ACETATE, 7768 -- -
===================== Product Identification ===================== Product ID:SODIUM ACETATE, 7768 MSDS Date:12/08/1996 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151; 800-424-9300 Resp. Party Other MSDS Num.:S2666 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID, SODIUM SALT CAS:127-09-3 RTECS #:AJ4300010 Minumum % Wt:99. Maxumum % Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ANHYDROUS: LD50: (ORAL, RAT) 3530 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION TO THE RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE COUGHING, SORE THROAT, LABORED BREATHING AND CHEST PAIN. INGESTION: LARGE DOSES MAY PRODUCE ABDOMINAL PAIN, NAUSEA, AND VOMITING. SKIN CONTACT: MAY CAUSE IRRITATION WITH REDNESS AND PAIN. EYE CONTACT: CONTACT MAY CAUSE IRRITATION, REDNESS AND PAIN. CHRONIC EXPOSURE: NO INFORMATION FOUND. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. INGESTION: GIVE SEVERAL GLASSES OF WATER TO DRINK TO DILUTE. IF LARGE AMOUNTS WERE SWALLOWED, GET MEDICAL ADVICE. S KIN CONTACT: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. GET MEDICAL A TTENTION IF IRRITATION DEVELOPS. EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION PER SISTS. ===================== Fire Fighting Measures ===================== Autoignition Temp:=611.C, 1131.8F Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:AS W/MOST ORGANIC SOLIDS, FIRE IS POSSIBLE AT ELEVATED TEMPERATURES OR BY CONTACT W/AN IGNITION SOURCE. LISTED FIRE DATA IS FOR THE ANHYDROUS MATERIAL. FINE DUST DISPERSED IN AIR IN SUFFICIENT CONCENT RATIONS, AND IN THE PRESENCE OF AN IGNITION SOURCE IS A POTENTIAL DUST EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. VENT AREA OF LEAK OR SPILL. WEAR APPROP PERSONAL PROT EQUIP AS SPECIFIED IN EXPOS CONTROLS/PERSONAL PROT. SPILLS: CLEAN UP SPILLS IN MANNER THAT DOES NOT DISPERSE DUST IN TO AIR. USE NON-SPKG TOOLS & EQUIP. REDUCE AIRBORNE DUST & PVNT SCATTERING BY MOISTENING W/WATER. PICK UP SPILL FOR RECOVERY OR DISPOSAL & PLACE IN CLOSED CNTNR. SMALL AMOUNTS OF RESIDUE (SUPDAT) ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM ANY SOURCE OF HEAT OR IGNITION. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, NIOSH APPRVD HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO TEN TIMES EXPOS LIMIT OR MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY OR RESP SUPPLIER, WHICHEVER IS LOWES T. NIOSH APPRVD FULL-FACE PIECE DUST/MIST RESP MAY BE WORN UP TO 50 TIMES EXPOS LIMIT OR MAX USE CONC SPECIFIED BY APPROP REGULATORY (SUPDAT) Ventilation:SYSTEM OF LOCAL &/OR GEN EXHAUST IS RECOM TO KEEP EMPLOYEE EXPOSURES BELOW AIRBORNE EXPOS LIMITS. LOCAL EXHAUST VENT GENERALLY PREFERRED (ECOLOGICAL INFO) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR CLEAN BODY-COVERING CLOTHING. Supplemental Safety and Health SPILL PROC: MAY BE FLUSHED TO SEWER W/PLENTY OF WATER. RESP PROT: AGENCY OR RESP SUPPLIER, WHICHEVER IS LOWEST. FOR EMERS OR INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPROVD FULL-FACEPIEC E POS-PRESS, AIR-SUPPLIED RESP. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=120.C, 248.F M.P/F.P Text:LOSES WATER Decomp Temp:=324.C, 615.2F Vapor Pres:NO INFO FOUND Vapor Density:NO INFO Spec Gravity:1.45 pH:8.9 Evaporation Rate & Reference:NO INFO FOUND Solubility in Water:76 GM/100MLS WATER @ 0C Appearance and Odor:COLORLESS CRYSTALS; SLIGHT ACETIC ACID ODOR. Percent Volatiles by Volume:0 @ 21C(70F) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NITRIC ACID, FLUORIDE, POTASSIUM NITRATE, STRONG OXIDIZERS AND DIKETENE. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. AVOID INCOMPATIBLES. Hazardous Decomposition Products:EMITS FUMES OF ACETIC ACID UPON HEATING AND ON CONTACT WITH STRONG ACIDS. =================== Toxicological Information =================== Toxicological Information:HYDRATE: INVESTIGATED AS A MUTAGEN. ANHYDROUS: ORAL RAT LD50: 3530 MG/KG; INHALATION RAT LC50: >30 G/M3; SKIN RABBIT LD50: >10 MG/KG; IRRITATION DATA, STANDARD DRAIZE: SKIN RABBIT 500 MG/24H, MILD; ST ANDARD DRAIZE, EYE RABBIT 10 MG, MILD. INVESTIGATED AS A MUTAGEN. CANCER LISTS: ACETIC ACID, SODIUM SALT (127-09-3): NTP CARCINOGEN - KNOWN-NO, ANTICIPATED-NO. IARC CATEGORY-NONE. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: NO INFORMATION FOUND. VENT: BECAUSE IT CAN CONTROL THE EMISSIONS OF THE CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO TH E GENERAL WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED PRACTICES, MOST RECENT EDITION, FOR DETAILS. AIRBORNE EXPOSURE LIMITS: -OSHA PERMISSIBLE EXPOSURE L IMIT (PEL): 15 MG/M3 TOTAL DUST, 5 MG/M3 RESPIRABLE FRACTION FOR NUISANCE DUSTS. -ACGIH THRESHOLD LIMIT VALUE 9TLV): 10 MG/M3 TOTAL DUST CONTAINING NO ASBESTOR & <1% CRYSTALLINE SILICA FOR PARTICULATE S NOT OTHERWISE CLASSIFIED (PNOC). ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE MANAGED IN AN APPROP & APPRVD WASTE DISPOSAL FACILITY. PROCESSING, USE OR CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL DISPOSAL REGS MAY DIFFER FROM FED DISPOSAL REGS. DISPOSE OF CNTNR & UNUSED CONTENTS I/A/W FEDE RAL, STATE & LOCAL REQUIREMENTS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. OTHER INFO: HERE FOR YOUR CONVENIENCE) - HEALTH RATING: 1-SLIGHT. FLAMMABILITY RATING: 0-NONE. REACTIVITY RATING: 0-NONE. CONTACT RATING: 1-SLIGHT. LAB PROTECTIVE EQUIP: GOGGLES; LAB CO AT. STORAGE COLOR CODE: ORANGE (GENERAL STORAGE). ===================== Regulatory Information ===================== SARA Title III Information:ACETIC ACID, SODIUM SALT (172-09-3): FEDERAL, STATE & INTERNATIONAL REGULATIONS - PART 1: SARA 302 - RQ-NO, TPQ-NO. SARA 313 - LIST-NO, CHEMICAL CATG-NO. SARA 311/312: ACUTE: YES, CHRONIC: NO. FIRE: N O. PRESSURE: NO. REACTIVITY: NO (MIXTURE/SOLID). Federal Regulatory Information:ACETIC ACID, SODIUM SALT (127-09-3): CHEMICAL INVEVENTORY STATUS - PART 1: TSCA-YES. EC-YES. JAPAN-YES. AUSTRALIA-YES. CHEMICAL INVENTORY STATUS - PART 2: KOREA-YES. CANADA - DSL-YES; NDSL-NO. PHIL-YE S. FEDERAL, STATE & INTERNATIONAL REGS - PART 2: RCRA CERCLA-NO. RCRA 261.33-NO. TSCA 8(D)-NO. CHEMICAL WEAPONS CONVENTION: NO. TSCA 12(B): NO. CDTA: NO. AUSTRALIAN HAZCHEM CODE: NO INFO FOUND. POISON SCHEDULE: NO INFO FOUND. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PRODUCTS REGS (CPR) & THE MSDS CONTAINS ALL OF THE INFO REQUIRED BY THE CPR. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.