EM INDUSTRIES -- FORMAMIDE, 4610 -- 6810-00N093025
===================== Product Identification ===================== Product ID:FORMAMIDE, 4610 MSDS Date:03/10/1999 FSC:6810 NIIN:00N093025 Status Code:A === Responsible Party === Company Name:EM INDUSTRIES Address:480 DEMOCRAT ROAD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Info Phone Num:856-423-6300 Emergency Phone Num:(800)424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:63612 === Contractor Identification === Company Name:E M SCIENCE DIV OF E M INDUSTRIES INC Address:480 DEMOCRAT ROAD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Phone:800-222-0342/609-423-6300 CAGE:63612 ============= Composition/Information on Ingredients ============= Ingred Name:FORMAMIDE CAS:75-12-7 RTECS #:LQ0525000 = Wt:100. ACGIH TLV:18 MG/M3;10 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 5570 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:IRRITATING ON CONTACT WITH SKIN, EYES OR MUCOUS MEMBRANES. INHALATION MAY IRRITATE NASAL AND RESPIRATORY PASSAGES. INGESTION CAN CAUSE HEADACHE, DIZZINESS, NAUSEA, LIVER INJURY. FORMAMIDE CAN BE ABSOR BED THROUGH THE SKIN. SPECIAL WARNING TO PREGNANT WORKERS: AVOID ANY EXPOSURE TO FORMAMIDE UNLESS ALL PRECAUTIONS ON MSDS ARE OBSERVED. SMALL AMOUNTS OF FORMAMIDE, IF REPEATEDLY INHALED, INGESTED OR A BSORBED THROUGH THE SKIN MAY CAUSE FETAL INJURY. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PREGNANCY. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: IMMEDIATELY FLUSH THOROUGHLY WITH LARGE AMOUNTS OF WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION: IF CONSCIOUS, DRINK WATER AND INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING B Y MOUTH TO AN UNCONSCIOUS PERSON. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:=154.4C, 310.F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:PRODUCES TOXIC FUMES ON THERMAL DECOMPOSITION. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE THE AREA OF ALL UNNECESSARY PERSONNNEL. WEAR SUITABLE PROTECTIVE EQUIPMENT LISTED UNDER EXPOSURE/PERSONAL PROTECTION. ELIMINATE ANY IGNITION SOURCES UNTIL THE AREA IS DETERMINED TO BE FREE FR OM EXPLOSION OR FIRE HAZARDS. CONTAIN THE RELEASE & ELIMINATE ITS SOURCE, IF THIS CAN BE DONE WITHOUT RISK. TAKE UP & CONTAINERIZE FOR PROPER DISPOSAL AS DESCRIBED UNDER DISPOSAL. COMPLY (SUPDAT) ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL AREA AWAY FROM IGNITION SOURCES. EXPLOSION-PROOF REFRIGERATOR RECOMMENDED FOR STORAGE. DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED (SEE TLV/PEL), A NIOSH APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS A LSO PERMIT OTHER NIOSH RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR SAFETY EQUIPMENT SUPPLIER). Ventilation:ENGINEERING &/OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOS. MATL MUST BE HANDLED OR TRANSFERRED IN APPRVD FUME HOOD OR W/EQUIVALENT VENT. Protective Gloves:PROTECTIVE GLOVES (BUTYL RUBBER, VITON OR EQUIVALENT). Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . IMPERVIOUS PROTECTIVE CLOTHING SHOULD BE WORN TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. Supplemental Safety and Health SPILL PROC: W/FEDERAL, STATE & LOCAL REGS ON REPORTING RELEASES. REFER TO REGULATORY INFO FOR REPORTABLE QUANTITY & OTHER REGULATORY DATA. EXPOSURE GUIDELINES: FORMAMIDE: OSHA-PEL: TWA: 20 PPM, 30 MG/ M3. STEL: 30 PPM, 45 MG/M3. ACGIH-TLV: TWA: 10 PPM; 18 MG/M3; SKIN. ================== Physical/Chemical Properties ================== Boiling Pt:=210.C, 410.F B.P. Text:DECOMPOSES Melt/Freeze Pt:=2.5C, 36.5F Vapor Pres:1 MM HG @ 70C Vapor Density:1.6(AIR=1) Spec Gravity:1.134 (H*2O=1) Evaporation Rate & Reference:>1 (BUAC=1) Solubility in Water:MISCIBLE Appearance and Odor:COLORLESS TO PALE YELLOW LIQUID; AMMONIA-LIKE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, BASES, OXIDIZERS, I*2, PYRIDINE, SO*3. Stability Condition to Avoid:HEAT; PROLONGED STORAGE. Hazardous Decomposition Products:CO*X, AMMONIA, NO*X, FORMIC ACID. =================== Toxicological Information =================== Toxicological Information:TOXICITY DATA: SKIN-RABBIT LDLO: 6000 MG/KG. TOXICOLOGICAL FINDINGS: TEST ON LABORATORY ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE MUTAGENIC AND REPRODUCTIVE EFFECTS. CITED IN REGISTRY OF TOXIC EFF ECTS OF CHEMICAL SUBSTANCES (RTECS). ==================== Disposal Considerations ==================== Waste Disposal Methods:TREATMENT: MATERIAL DOES NOT HAVE AN EPA WASTE NUMBER AND IS NOT A LISTED WASTE, HOWEVER, CONSULTATION WITH A PERMITTED WASTE DISPOSAL SITE (TSD) SHOULD BE ACCOMPLISHED. ALWAYS CONTACT A PERMITTED WAS TE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME: OTHER REGULATED SUBSTANCE, LIQUID, N.O.S. (FORMAMIDE). DOT ID NUMBER: NA3082. ===================== Regulatory Information ===================== Federal Regulatory Information:THE CAS NUMBER OF THIS PRODUCT IS LISTED ON THE TSCA INVENTORY. FORMAMIDE - OSHA FLOOR LIST: YES. State Regulatory Information:COMMENTS: NONE. NFPA HAZARD RATINGS - HEALTH: 2; FLAMMABILITY: 1; REACTIVITY: 0. REVISION HISTORY: 8/1/81; 3/7/86; 6/1/87; 10/27/87; 12/8/89; 3/1/91; 4/30/93; 1/13/96; 5/15/96. REVISED SECTION: CHEMIC AL PROD & COMPANY IDENTIFICATION. N/A = NOT AVAILABLE. N/E = NONE ESTABLISHED. PROD IDENTIFICATION: SYNONYMS: METHANAMIDE; CHEM FAMILY: AMIDE; FORMULA: HCONH*2; MOLECULAR WT: 45.04. EMER OVERVIEW: HAR MFUL IF INHALED, SWALLOWED OR ABSORBED THRU SKIN. POSS BIRTH DEFECT HAZ. MAY CAUSE BIRTH DEFECTS BAS ED ON ANIMAL DATA. IRRITATING TO SKIN, EYES & MUCOUS MEMBRANES. HYGROSCOPIC. APPEAR: COLORLESS TO PALE YELLOW LIQUID; AMMONIA-LIKE ODOR. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.