MALLINCKRODT INC,SCIENCE PRODUCTS DIVISION -- LEAD METAL -- 6810-00N010366
===================== Product Identification ===================== Product ID:LEAD METAL MSDS Date:08/08/1985 FSC:6810 NIIN:00N010366 === Responsible Party === Company Name:MALLINCKRODT INC,SCIENCE PRODUCTS DIVISION Box:M City:PARIS State:KY ZIP:40361 Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Other REC Limits:N/K OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:LEAD IS A CUMULATIVE POISON & EXPOSURE EVEN TO SMALL AMOUNTS CAN RAISE THE BODY'S CONTENT TO TOXIC LEVELS.SYMPTOMS OF CHRONIC EXPOSURE ARE LIKE THOSE OF INGESTION POISONING;RESTLESSNESS AND IRRITABILI TY MAY ALSO BE NOTED. Explanation of Carcinogenicity:INORGANIC LEAD & LEAD COMPOUNDS:INAD EVID FOR CARCIN IN HUM;SUFF EVID FOR CARCIN IN ANIM (IARC 1987). Effects of Overexposure:EYES:IRRIT & ABRASION.ABSORPTION THROUGH EYE IS POSS.SKIN:IRRIT & REDNESS.MAY BE ABSORBED ON PROLONGED EXPOS CAUSING SYMP LIKE INGEST.INGEST:ABDOM PAIN & SPASMS,NAUSEA,VOM,HEADACHE.ACUTE POISONING-MUS CLE WEAK,"LEAD LINE" ON GUMS,METALLIC TASTE,LOSS OF APPETITE,INSOMNIA,DIZZ,HIGH LEAD LEVELS IN BLOOD & URINE, (SEE SUPP) Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING NERVE OR CIRCULATORY DISORDERS OR WITH SKIN OR EYE PROBLEMS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS DISEASE. ======================= First Aid Measures ======================= First Aid:EYES:WASH WITH PLENTY OF WATER FOR AT LEAST 15 MIN.CALL MD.SKIN:WASH EXPOSED AREA WITH SOAP AND WATER. GET MEDICAL ADVICE IF IRRIT DEVELOPS.INGEST:INDUCE VOMITING IMMEDIATELY BY GIVING 2 GLASSES OF WA TER AND STICKING FINGER DOWN THROAT.CALL MD IMMEDIATELY.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.INHALATION:REMOVE TO FRESH AIR.GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. ===================== Fire Fighting Measures ===================== Flash Point:N/K Lower Limits:N/K Upper Limits:N/K Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE OR EXPLOSION HAZARD.HAZ DECOMP PROD:CAN PRODUCE TOXIC LEAD FUMES AND LEAD OXIDE FUMES AT ELEVATED TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN-UP PERSONNEL NEED PROT CLOTHING AND RESP EQUIP FOR DUSTS.SWEEP,SCOOP,OR PICK UP MATL.VACUUMING/WET SWEEPING MAY AVOID DUST DISPERSAL.PACKAGE FOR RECLAMATION OR RECOVERY.PACKAGE UNRECLAIMABLE MAT L FOR DISPOSAL IN RCRA APPROVED WASTE FACILITY. Neutralizing Agent:N/K ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR TIGHTLY CLOSED.STORE IN COOL,DRY VENT AREA.PROTECT FROM PHYSICAL DMG.ISOLATE FROM INCOMPATIBLE SUBSTANCES.AVOID BREATHING DUST. Other Precautions:MAINTAIN EYEWASH & QUICK-DRENCH FACILITY.EATING,DRINKING,& SMOKING SHOULD NOT BE PERMITTED WHERE EXPOS TO SOLIDS OR LIQUIDS CONTAINING SOL LEAD CMPDS ARE HANDLED,PROCESSED OR STORED.AREAS OF POSS EXP SHOULD BE MARKED & ACCESS (SEE SUPP) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Protective Gloves:WEAR IMPERVIOUS GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING,INCLUDING BOOTS,LAB COAT,APRON OR COVERALLS TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health VP:1.77 MMHG @ 1000C (1832F).SIGNS & SYMP:WITH SHOCK,COMA,& DEATH IN EXTREME CASES.INHAL:IRRIT OF BRONCHI & LUNGS.ACUTE EXPOS-METALLIC TASTE,CHEST & ABDOMINAL PAIN,& INCREASED LEAD BLOOD LEVELS.ABSORP TION THROUGH RESPIRATORY SYSTEM IS POSSIBLE.OTHER PREC:TO SUCH AREAS SHOULD BE LIMITED TO AUTHORIZED PERSONS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:1740C Melt/Freeze Pt:M.P/F.P Text:327.5C Decomp Temp:Decomp Text:N/K Vapor Pres:SEE SUPP Spec Gravity:11.34 (WATER=1) Solubility in Water:INSOLUBLE Appearance and Odor:SMALL,BLUE-GRAY,ODORLESS GRANULES. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AMMONIUM NITRATE,CHLORINE TRIFLUORIDE,HYDROGEN PEROXIDE. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. Hazardous Decomposition Products:DOES NOT DECOMPOSE BUT TOXIC LEAD OR LEAD OXIDE FUMES MAY FORM AT ELEVATED TEMPERATURES. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.