EM SCIENCE -- ACETONITRILE, AX0142GN -- 6810-00N076006
===================== Product Identification ===================== Product ID:ACETONITRILE, AX0142GN MSDS Date:06/30/1994 FSC:6810 NIIN:00N076006 === Responsible Party === Company Name:EM SCIENCE Address:480 DEMOCRAT RD City:GIBBSTOWN State:NJ ZIP:08027 Country:US Info Phone Num:609-423-6300 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:DO242 === Contractor Identification === Company Name:E M SCIENCE DIV OF E M INDUSTRIES INC Address:480 DEMOCRAT ROAD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Phone:800-222-0342/609-423-6300 CAGE:63612 Company Name:EM SCIENCE Address:480 DEMOCRAT RD City:GIBBSTOWN State:NJ ZIP:08927 Phone:800-424-9300 (CHEMTREC) CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONITRILE (SARA 313) (CERCLA) CAS:75-05-8 RTECS #:AL7700000 Fraction by Wt: 100% OSHA PEL:40 PPM ACGIH TLV:40 PPM; 60 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPDAT: PROCESS OPERATING UNDER VACUUM IF SUBJECTED TO SUDDEN INGRESS OF AIR OR OUTSIDE PROCESS EQUIPMENT (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: OPERATING UNDER ELEVATED PRESSURE IF SUDDEN ESCAPE OF VAPORS OR MISTS TO THE ATMOSPHERE OCCURS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. RTECS #:9999999ZZ Ingred Name:SPILL PROC: & ELIMINATE ITS SOURCE IF THIS CAN BE DONE W/OUT RISK. TAKE UP & CONTAINERIZE FOR PROPER DISPOSAL AS (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: DESCRIBED UNDER DISPOSAL. COMPLY W/FEDERAL, STATE & LOCAL REGS ON REPORTING RELEASES. REFER TO REGULATORY (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: INFO FOR REPORTABLE QUANTITY & OTHER REGULATORY DATA. MFR RECOMMENDS SPILL-X ABSORBENT AGENTS FOR VARIOUS (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: TYPES OF SPILLS. ADDITIONAL INFO ON SPILL-X PRODS CAN BE PROVIDED THROUGH EM SCIENCE TECHNICAL SERVICE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: DEPARTMENT 609-354-9200. SOLVENT SPILL TREATMENT KIT - SX0863 ABSORBENT IS RECOMMENDED FOR THIS PRODUCT. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. RTECS #:9999999ZZ Ingred Name:RESP PROT:(NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE SAFETY EQUIPMENT SUPPLIER). ENGINEERING &/OR (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 2730 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TOXIC BY INGESTION, INHALATION AND SKIN ABSORPTION. CAUSES HEADACHE, BREATHING DIFFICULTY, IRRITATION OF EYES AND THROAT, CENTRAL NERVOUS SYSTEM DISTURBANCES, UNCONSCIOUSNESS. AFFECTS LUNGS, KIDNEYS, LIVER, CNS AND REPRODUCTIVE ORGANS. BREATHING HIGH CONCENTRATIONS MAY CAUSE CYANIDE POISONING AND (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: DEATH. EFFECTS MAY BE DELAYED. TESTS ON LABORATORY ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE MUTAGENIC AND REPRODUCTIVE EFFECTS. Medical Cond Aggravated by Exposure:RESPIRATORY, KIDNEY AND LIVER CONDITIONS. ======================= First Aid Measures ======================= First Aid:GET MED ASSISTANCE FOR ALL CASES OF OVEREXP. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: IMMED FLUSH THOROUGHLY W/WATER FOR AT LEAST 15 MIN. INHAL: REMOVE TO FRESH AIR; GIVE ARTF RESP IF BREATHING HAS STOPPED. HAVE PATIENT BREATHE AMYL NITRITE VAPOR FOR 15 SECONDS AT 15 SECOND INTERVALS (5 TIMES). INGEST: IF CONSCIOUS, DRINK WATER & INDUCE VOMITING IMMED AS DIRECTED BY MED PERSONNEL. (ING 4) ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:42.0F,5.6C Lower Limits:4.40% Upper Limits:16.00% Extinguishing Media:ALCOHOL FOAM, DRY CHEMICAL, WATER SPRAY. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DANGEROUS FIRE & EXPLO HAZ. VAP CAN TRAVEL DISTANCES TO IGNIT SOURCE & FLASH BACK. HOT ORGANIC CHEM VAPS OR MISTS ARE SUSCEPTIBLE TO SUDDEN SPONTANEOUS (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE THE AREA OF ALL UNNECESSARY PERSONNEL. WEAR SUITABLE PROTECTIVE EQUIPMENT LISTED UNDER EXPOS/PERSONAL PROT. ELIMINATE ANY IGNITION SOURCES UNTIL THE AREA IS DETERMINED TO BE FREE FROM EXPLOSI ON OR FIRE HAZARDS. CONTAIN THE RELEASE(ING 5) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO NOT BREATHE VAPOR. Other Precautions:ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS PRODUCT. RETAINED RESIDUE MAY MAKE EMPTY CONTAINERS HAZARDOUS; USE CAUTION! DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED, A NIOSH APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTH ER NIOSH APPROVED RESPIRATORS (ING 11) Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH EQUIVALENT VENTILATION. Protective Gloves:BUTYL RUB, NEOPRENE, PVA OR EQUIVALENT. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. Supplemental Safety and Health EXPLO HAZ: COMBUSTION WHEN MIXED W/AIR. IGNITION MAY OCCUR AT TEMPS BELOW PUBLISHED AUTOIGNITION OR IGNITION TEMPS. IGNITION TEMPS DECREASE W/INCREASING VAPOR VOLUME & VAPOR/AIR CONTACT TIME & ARE INF LUENCED BY PRESSURE CHANGES. IGNITION MAY OCCUR AT TYPICAL ELEVATED TEMP PROCESS CONDITIONS, ESPECIALLY IN (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:180F,82C Melt/Freeze Pt:M.P/F.P Text:-49F,-45C Vapor Pres:72.8 @ 20C Vapor Density:1.41 Spec Gravity:0.786 (H*2O=1) Evaporation Rate & Reference:5.79 (BUAC=1) Solubility in Water:MISCIBLE Appearance and Odor:COLORLESS LIQUID; AROMATIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ACIDS, OXIDIZERS. Stability Condition to Avoid:HEAT; CONTACT WITH IGNITION SOURCE. WILL REACT WITH WATER, STEAM OR ACIDS TO PRODUCE TOXIC AND FLAMMABLE VAPORS. Hazardous Decomposition Products:HCN, CO*X, NO*X, (FORMS HCN WHEN HEATED ABOUT 120C). ==================== Disposal Considerations ==================== Waste Disposal Methods:SPECIFIED TECHNOLOGY - INCINERATION TO A LEVEL BELOW TCA (TOTAL CONSTITUENT ANALYSES) LEVELS. CONTACT LOCAL PERMITTED WASTE DISPOSAL COMPANY (TSD) FOR PERMISSIBLE TREATMENT SITE. ALWAYS CONTACT PERMIT TED WASTE DISPOSER (TSD) TO ASSURE (ING10) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.