CITGO PETROLEUM CORP -- SUPERGARD SAE 10W-40, 20-814 -- 9150-00N038744
=====================  Product Identification  =====================

Product ID:SUPERGARD SAE 10W-40, 20-814
MSDS Date:07/12/1991
FSC:9150
NIIN:00N038744
=== Responsible Party ===
Company Name:CITGO PETROLEUM CORP
Box:3758
City:TULSA
State:OK
ZIP:74102
Country:US
Info Phone Num:918-495-5933
Emergency Phone Num:318-491-6215;800-424-9300(CHEMTREC)
CAGE:1JW40
=== Contractor Identification ===
Company Name:CITGO PETROLEUM CORP
Address:OFF HWY 108
Box:3758
City:LAKE CHARLES
State:LA
ZIP:70602
Country:US
Phone:918-561-5165
CAGE:1JW40
Company Name:CITIES SERVICE CO
Address:110 W 7TH
Box:300
City:TULSA
State:OK
ZIP:74102
Country:US
CAGE:12518

=============  Composition/Information on Ingredients  =============

Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED
    (SEVERE) LIGHT PARAFFINIC; (REFINED PETROLEUM DISTILLATES)
CAS:64741-89-5
RTECS #:PY8041501
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)

Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY
    PARFFINIC (SEVERE SOLVENT-REFINING &/OR HYDROTREATMENT);(ING5)
CAS:64742-65-0
RTECS #:PY8038501
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)

Ingred Name:ING 4: (REFINED PETROLEUM DISTILLATES)
RTECS #:9999999ZZ

Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE)
    HEAVY PARAFFINIC; (REFINED PETROLEUM DISTILLATES)
CAS:64742-54-7
RTECS #:PY8035501
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)

Ingred Name:ANTI-WEAR, ANTI-OXIDANT, ANTI-RUST ADDITIVE; (ANTIWEAR,
    RUST & OXID INHIBITORS (CNTNS ZINC DIALKYLDITHIOPHOSPHATES))
Fraction by Wt: <15%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:VI-IMPROVER. LD50:(ORAL,RAT)>5G/KG
Fraction by Wt: <15%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:POUR POINT DEPRESSANT
Fraction by Wt: <1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPP DATA: RECYCLING OR DISPOSING OF EMTPY CONTAINERS &/OR
    WASTE RESIDUES OF THIS PRODUCT.
RTECS #:9999999ZZ

Ingred Name:VENT: MANDATED STD. RESPONSIBLE INDIVIDUALS SHOULD EVALUATE
    AIR CONC OF SPECIFIC REGULATED CHEMICALS.
RTECS #:9999999ZZ

Ingred Name:REFINED PETROLEUM DISTILLATES (CONTAINING INGS 2-5).
    LD50:(ORAL,RAT)>5G/KG
RTECS #:9999999ZZ
Fraction by Wt: >75%

Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED(SEVERE)
    HEAVY PARAFFINIC; (REFINED PETROLEUM DISTILATES)
CAS:64741-88-4
RTECS #:PY8040501
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: LOW RISK @ AMBIENT
    TEMPS. MISTS/FUMES MAY CAUSE DIZZ, HDCH, NAUS, RESP IRRIT/CHEM
    PNEUM. SKIN: TRANSIENT, SLIGHT IRRIT. EYE: PRACTICALLY
    NON-IRRITANT. INGEST: LOW TOX. @ A SAYBOLT VISCOS ITY OF 500
    SUS(100F), RISK OF ASPIR INTO LUNGS IS REDUCED. IF LESS THAN 1OZ IS
    INGESTED, MATL MAY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: PASS THRU SYS W/OUT HARM. ON INGEST
    OF LG QTY SLIGHT GI DISCOMFORT, DIARR, & HDCH MAY OCCUR. INGECTION:
    SUBCUTANEOUS/INTRAMUSCULAR INJECTION MAY CAUSE IRRIT, ERYTHEMA,
    EDEMA. CHRONIC: DERMAL , PROLONGED AND REPEATED EXPOSURE MAY CAUSE
    DRYING OF SKIN.
Medical Cond Aggravated by Exposure:NONE.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE FROM EXPOS TO INCIDENTAL FUMES & PROVIDE RESP
    SUPPORT IF NEC. SKIN:WASH W/SOAP & WATER. EYES:FLUSH W/LG VOL OF
    WATER FOR @ LST 15 MIN. INGEST:INDUCE VOMIT & SEEK MED AID.
    INJECTION:SEEK M ED AID. NOTES TO PHYS: FOLLOWING INGEST, @ A
    SAYBOLT VISCOSITY OF 500 @ 100F, RISK OF ASPIR INTO LUNGS IS
    REDUCED. FOR QTY ABOVE 1 OZ, EMESIS/LAVAGE MAY BE CONSIDERED.
    SUBCUTANEOUS INJECTION (SUPDAT)

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:379F,193C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING.

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE SOURCES OF HEAT/IGNIT. PROVIDE ADEQ
    VENT. SM SPILLS: TAKE UP W/NONCOMBUST ABSORB SUCH AS FULLERS
    EARTH/SAND. PLACE INTO CONTRS FOR LATER DISP. LG SPILLS:CNTN SPILL
    IN EARTHEN DIKES FOR LATER RE COVERY. CTL IGNIT SOURCES AROUND
    SPILL (SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD & AWAY FROM
    HEAT & FLAME.AVOID PRLNGD SKIN CONT W/USED MOTOR OILS. CONTINUOUS
    CONT W/USED OIL HAS CAUSE CANCER IN LAB ANIMALS.
Other Precautions:AFTER DRAINING OIL, WASH SKIN THORO WITH SOAP AND
    WATER. EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE WHICH COULD
    INCLUDE FLAMMABLE OR EXPLOSIVE VAPORS.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF HIGH VAPOR CONCENTRATION IS EXPECTED, USE
    NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE IN WELL VENTD AREA. IN CONFINED SPACES, MECH VENT MAY
    BE REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (ING 11)
Protective Gloves:OIL IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WEAR BODY-COVERING WORK CLOTHES TO AVOID
    PROLONGED OR REPEATED EXPOSURE. LAUNDER SOILED WORK CLOTHES BEFORE
    REUSE.
Work Hygienic Practices:AFTER DRAINING OIL, WASH SKIN THOROUGHLY WITH
    SOAP AND WATER.
Supplemental Safety and Health
SPEC GRAV: 0.89@60F(H*2O=1). VP: <1X10*3@25C. FIRST AID PROC: REQ
    PROMPT SURGICAL DEBRIDEMENT. IF NOT FAMILIAR W/TECH, SEEK SKILLED
    ADVICE. SPILL PROC: AREA. RPT SPILLS AS REQD TO APPROP AUTH. WASTE
    D ISP METH: #:800-424-9300. CONSULT APPROP FED, ST & LOC AUTH
    BEFORE REUSING, RECONDITIONING, RECLAIMING, (ING 10)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:760F,404C
Vapor Pres:SUPP DATA
Vapor Density:>1
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:<1(BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER, SLIGHT PETROLEUM ODOR.
Percent Volatiles by Volume:NEGLIG

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, STRONG ACIDS, CAUSTICS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, (CARBON MONOXIDE UNDER
    INCOMPLETE COMBUSTION), TRACES OF OXIDES OF CA, MG, P, S, ZN.

====================  Disposal Considerations  ====================

Waste Disposal Methods:IT IS THE RESPONSIBILITY OF USER TO DETERM IF
    MATL IS A HAZ WASTE @ TIME OF DISP. CHECK BEFORE DISPOSING TO BE
    SURE THAT YOUR ARE IN COMPLIANCE W/ALL APPLIC LAWS & REGS. TREAT
    USED OIL ACCDG TO CURREN T RULES & REGS. CHEMTREC/RCRA EMER
    HOTLINE(SUPDAT)

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