CITGO PETROLEUM CORP -- SUPERGARD SAE 10W-40, 20-814 -- 9150-00N038744
===================== Product Identification ===================== Product ID:SUPERGARD SAE 10W-40, 20-814 MSDS Date:07/12/1991 FSC:9150 NIIN:00N038744 === Responsible Party === Company Name:CITGO PETROLEUM CORP Box:3758 City:TULSA State:OK ZIP:74102 Country:US Info Phone Num:918-495-5933 Emergency Phone Num:318-491-6215;800-424-9300(CHEMTREC) CAGE:1JW40 === Contractor Identification === Company Name:CITGO PETROLEUM CORP Address:OFF HWY 108 Box:3758 City:LAKE CHARLES State:LA ZIP:70602 Country:US Phone:918-561-5165 CAGE:1JW40 Company Name:CITIES SERVICE CO Address:110 W 7TH Box:300 City:TULSA State:OK ZIP:74102 Country:US CAGE:12518 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED (SEVERE) LIGHT PARAFFINIC; (REFINED PETROLEUM DISTILLATES) CAS:64741-89-5 RTECS #:PY8041501 OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARFFINIC (SEVERE SOLVENT-REFINING &/OR HYDROTREATMENT);(ING5) CAS:64742-65-0 RTECS #:PY8038501 OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:ING 4: (REFINED PETROLEUM DISTILLATES) RTECS #:9999999ZZ Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE) HEAVY PARAFFINIC; (REFINED PETROLEUM DISTILLATES) CAS:64742-54-7 RTECS #:PY8035501 OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:ANTI-WEAR, ANTI-OXIDANT, ANTI-RUST ADDITIVE; (ANTIWEAR, RUST & OXID INHIBITORS (CNTNS ZINC DIALKYLDITHIOPHOSPHATES)) Fraction by Wt: <15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VI-IMPROVER. LD50:(ORAL,RAT)>5G/KG Fraction by Wt: <15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POUR POINT DEPRESSANT Fraction by Wt: <1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPP DATA: RECYCLING OR DISPOSING OF EMTPY CONTAINERS &/OR WASTE RESIDUES OF THIS PRODUCT. RTECS #:9999999ZZ Ingred Name:VENT: MANDATED STD. RESPONSIBLE INDIVIDUALS SHOULD EVALUATE AIR CONC OF SPECIFIC REGULATED CHEMICALS. RTECS #:9999999ZZ Ingred Name:REFINED PETROLEUM DISTILLATES (CONTAINING INGS 2-5). LD50:(ORAL,RAT)>5G/KG RTECS #:9999999ZZ Fraction by Wt: >75% Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED(SEVERE) HEAVY PARAFFINIC; (REFINED PETROLEUM DISTILATES) CAS:64741-88-4 RTECS #:PY8040501 OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: LOW RISK @ AMBIENT TEMPS. MISTS/FUMES MAY CAUSE DIZZ, HDCH, NAUS, RESP IRRIT/CHEM PNEUM. SKIN: TRANSIENT, SLIGHT IRRIT. EYE: PRACTICALLY NON-IRRITANT. INGEST: LOW TOX. @ A SAYBOLT VISCOS ITY OF 500 SUS(100F), RISK OF ASPIR INTO LUNGS IS REDUCED. IF LESS THAN 1OZ IS INGESTED, MATL MAY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: PASS THRU SYS W/OUT HARM. ON INGEST OF LG QTY SLIGHT GI DISCOMFORT, DIARR, & HDCH MAY OCCUR. INGECTION: SUBCUTANEOUS/INTRAMUSCULAR INJECTION MAY CAUSE IRRIT, ERYTHEMA, EDEMA. CHRONIC: DERMAL , PROLONGED AND REPEATED EXPOSURE MAY CAUSE DRYING OF SKIN. Medical Cond Aggravated by Exposure:NONE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOS TO INCIDENTAL FUMES & PROVIDE RESP SUPPORT IF NEC. SKIN:WASH W/SOAP & WATER. EYES:FLUSH W/LG VOL OF WATER FOR @ LST 15 MIN. INGEST:INDUCE VOMIT & SEEK MED AID. INJECTION:SEEK M ED AID. NOTES TO PHYS: FOLLOWING INGEST, @ A SAYBOLT VISCOSITY OF 500 @ 100F, RISK OF ASPIR INTO LUNGS IS REDUCED. FOR QTY ABOVE 1 OZ, EMESIS/LAVAGE MAY BE CONSIDERED. SUBCUTANEOUS INJECTION (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:379F,193C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF HEAT/IGNIT. PROVIDE ADEQ VENT. SM SPILLS: TAKE UP W/NONCOMBUST ABSORB SUCH AS FULLERS EARTH/SAND. PLACE INTO CONTRS FOR LATER DISP. LG SPILLS:CNTN SPILL IN EARTHEN DIKES FOR LATER RE COVERY. CTL IGNIT SOURCES AROUND SPILL (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD & AWAY FROM HEAT & FLAME.AVOID PRLNGD SKIN CONT W/USED MOTOR OILS. CONTINUOUS CONT W/USED OIL HAS CAUSE CANCER IN LAB ANIMALS. Other Precautions:AFTER DRAINING OIL, WASH SKIN THORO WITH SOAP AND WATER. EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE WHICH COULD INCLUDE FLAMMABLE OR EXPLOSIVE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF HIGH VAPOR CONCENTRATION IS EXPECTED, USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS. Ventilation:USE IN WELL VENTD AREA. IN CONFINED SPACES, MECH VENT MAY BE REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (ING 11) Protective Gloves:OIL IMPERVIOUS GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:WEAR BODY-COVERING WORK CLOTHES TO AVOID PROLONGED OR REPEATED EXPOSURE. LAUNDER SOILED WORK CLOTHES BEFORE REUSE. Work Hygienic Practices:AFTER DRAINING OIL, WASH SKIN THOROUGHLY WITH SOAP AND WATER. Supplemental Safety and Health SPEC GRAV: 0.89@60F(H*2O=1). VP: <1X10*3@25C. FIRST AID PROC: REQ PROMPT SURGICAL DEBRIDEMENT. IF NOT FAMILIAR W/TECH, SEEK SKILLED ADVICE. SPILL PROC: AREA. RPT SPILLS AS REQD TO APPROP AUTH. WASTE D ISP METH: #:800-424-9300. CONSULT APPROP FED, ST & LOC AUTH BEFORE REUSING, RECONDITIONING, RECLAIMING, (ING 10) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:760F,404C Vapor Pres:SUPP DATA Vapor Density:>1 Spec Gravity:SUPP DATA Evaporation Rate & Reference:<1(BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:AMBER, SLIGHT PETROLEUM ODOR. Percent Volatiles by Volume:NEGLIG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS, STRONG ACIDS, CAUSTICS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, (CARBON MONOXIDE UNDER INCOMPLETE COMBUSTION), TRACES OF OXIDES OF CA, MG, P, S, ZN. ==================== Disposal Considerations ==================== Waste Disposal Methods:IT IS THE RESPONSIBILITY OF USER TO DETERM IF MATL IS A HAZ WASTE @ TIME OF DISP. CHECK BEFORE DISPOSING TO BE SURE THAT YOUR ARE IN COMPLIANCE W/ALL APPLIC LAWS & REGS. TREAT USED OIL ACCDG TO CURREN T RULES & REGS. CHEMTREC/RCRA EMER HOTLINE(SUPDAT) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.