FISHER SCIENTIFIC CHEMICAL -- MERCURIC CHLORIDE, M156 -- 6810-00-477-2943
===================== Product Identification ===================== Product ID:MERCURIC CHLORIDE, M156 MSDS Date:06/17/1997 FSC:6810 NIIN:00-477-2943 Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-769-7100 Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:MERCURIC CHLORIDE (SARA 302/313) (CERCLA) LD50 (ORAL RAT): 1 MG/KG CAS:7487-94-7 RTECS #:OV9100000 Fraction by Wt: 100% OSHA PEL:0.1 MG (HG)/M3 ACGIH TLV:0.025 MG(HG)/M3,S Ingred Name:SUP DAT: DEATH MAY OCCUR IN THIS PHASE FROM RENAL FAILURE. MEAN LETHAL DOSE FOR ADULTS IS 1-4 G. CHRONIC: INHAL: (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: INHAL OVER LONG PERIOD MAY CAUSE MERCURIALISM & MAY INCL TREMORS, SALIVATION, INFLAMM OF MOUTH, LOOSENING (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: OF TEETH, BLUE LINE ON GUMS, PAIN & NUMBNESS IN EXTREMITIES, DIARR, ANXIETY, HDCH, WT LOSS, DEPREE, (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: INSTABILITY & HALLUCINATIONS. SKIN MAY CAUSE IRRT & SENSIT DERM. MAY RSLT IN PSYCHIC DISTURB, PERIPHERAL(ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: NEUROPATHY & KIDNEY DMG. EYE: NOT REPORTED IN HUMANS. INGEST: PRINCIPAL MANIFESTATIONS OF CHRONIC POIS (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: ARE METALLIC TASTE, EXCESS SALIVATION, GINGIVITIS, PYORRHEA W/LOOSENING OF TEETH, DIGESTIVE DISORDERS, (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: ABDOM DISTREE & SKIN ERUPTIONS PREGRESSING TO DERM. LIVER & KIDNEY DMG MAY OCCUR. PERSONALITY CHANGES (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: HAVE BEEN ASSOC W/CHRONIC MERCURIAL POIS. MERCURY APPEARS ON NAVY OCCUP CHEM REPRO HAZ LIST. SEEK CONSULT(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HANDLING & EXPOS INFO . (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: CONTACT NEHC FOR MORE SPECIFIC INFORMATION ON HEALTH HAZARDS . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: EYE: WASH IMMED W/LGE AMTS OF WATER, OCCAS LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: CHEM REMAINS (AT LEAST 15-20 MIN). CONTINUE IRRIGATING W/NORM SALINE UNTIL PH HAS RETURNED TO NORM (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: (30-60 MIN). COVER W/STERILE BANDAGES. GET MED ATTN IMMED. INGEST: REMOVE BY GASTRIC LAVAGE/EMESIS. (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: MAINTAIN BLOOD PRESS & AIRWAY. GIVE OXYGEN IF RESP DEPRESSED. DO NOT PERFORM GASTRIC LAVAGE/EMESIS IF (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: UNCON. GET MED ATTN IMMED. ADMIN OF GASTRIC LAVAGE/OXYGEN SHOOULD BE PERFORMED BY QUALIFIED MED PERS. (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: ANTIDOTE: MERCURY POIS: GIVE DIMERCAPROL, 3 MG/KG (OR 0.3 ML/10 KG) EVERY 4 HRS FOR FIRST 2 DAYS & THEN (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: 2 MG/KG EVERY 12 HRS FOR TOTAL OF 10 DAYS IF NEC. DIMERCAPROL IS AVAIL AS 10% SOLN IN OIL FOR INTRAMUSC (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: ADMIN. HEMODIALYSIS WILL SPEED REMOVAL OF MERCURY-DIMECAPROL COMPLEX. PENICILLAMINE IS ALSO EFFECTIVE. (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: GIVE UP TO 100 MG/KG/DAY (MAX 1 G/DAY) DIVIDED INTO 4 DOSES FOR NO LONGER THAN 1 WK. IF LONGER ADMIN (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: PERIOD IS WARRANTED, DOSAGE SHOULD NOT EXCEED 40 MG/KG/DAY. GIVE DRUG ORALLY HALF HR BEFORE MEALS. A (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: CHELATING AGENT SHOULD BE CONTINUED UNTIL URINE-MERCURY LEVEL FALLS < 50 UG/24HRS. ANTIDOTE SHOULD BE (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22: ADMINISTERED BY QUALIFIED MEDICAL PERSONNEL. RTECS #:9999999ZZ Ingred Name:SPILL PROC: AHEAD OF SPILL FOR LATER DISP. ISOLATE HAZ AREA & DENY ENTRY. REPORTABLE QUANTITY (RQ): 1 POUND. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: TOXICITY CHARACTERISTIC & MUST BE DISP OF I/A/W 40 CFR PART 262. EPA HAZARDOUS WASTE NUMBER D009. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: IRRIT/NEUROTOXIN/NEPHROTOXIN. 28 MG/M3 IDLH. HIGH DUST CONCS MAY CAUSE SORE THROAT, COUGH, DYSPNEA, LABORED BRTHG & DELAYED PULM EDEMA. HIGH VAP CONC CAN CAUSE IMMED DYSPNEA, COUGH, FEVE R, NAUS, VOMIT, DIARR, INFLAMM OF MOUTH, SALIVATION & METALLIC TASTE. SKIN: MAY CAUSE REDNESS & (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: IRRIT. SENSIT DERM MAY OCCUR. MAY BE ABSORBED THRU INTACT SKIN CAUSING ANURIA. EYE: DIRECT CONT HAS CAUSED SEV BURNS IN HUMAN EYES. IN VERY RARE INSTANCES VISION HAS RECOVERED, DESPITE SEV D MG & NECROSIS. INGEST: NECROSIS BEGINS IMMED IN MOUTH, THROAT, ESOPHAGUS & STOM. W/IN FEW MIN, VIOLENT PAIN, (SUP DAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMIN OXYGEN IF AVAIL. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. ADMIN OF OXYGEN SH OULD BE PERFORMED BY QUALIFIED PERS. GET MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH AREA W/SOAP & WATER UNTIL NO EVIDENCE OF CHEM REMAINS (15-20 MIN). GET MED ATTN IMMED. (ING 12) ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE CONTR FROM FIRE IF POSS. USE WATER IN FLOODING AMTS AS FOG. AVOID BRTHG POIS DUSTS & FUMES FROM FIRE. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH MATL. STOP LEAK IF W/OUT RISK. SML SPILL: TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CONTNRS FOR DISP. SML DRY SPILL: W/CLEAN SHOVEL PLACE MATL INTO CLEAN, DRY CONTR & COVER. MOVE CONT R FROM SPILL AREA. LGE SPILL: DIKE FAR (ING 24) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS. MAY BURN BUT DOES NOT IGNITE READILY. PREVENT DISPERSION OF DUST IN AIR. Other Precautions:DO NOT ALLOW SPILLED MATERIAL TO CONTAMINATE WATER SOURCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESP MUST BE NIOSH APPRVD. MERCURY VAP: 0.5 MG/M3: ANY CHEM CATRIDGE RESP W/CARTRIDGES PROVIDING PROT AGAINST MERCURY VAP; 1,25 MG/M3: ANY SUPP-AIR RESP OPERATED IN CONTINUOUS-FLOW MODE. CONT NEHC FO R COMPLETE LIST OF APPRVD RESPS . Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM TO MEET PUBLISHED EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:NIOSH APPRVD EMER EYEWASH & DELUGE SHOWER . WEAR APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT SKIN CONT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EFTS OF OVEREXP: PROFUSE VOMIT & SEV PURGING MAY OCCUR. PATIENT MAY DIE W/IN FEW MIN FROM FLUID/ELECTROLYTE LOSSES & PERIPHERAL VASCULAR COLLASPE, BUT DEATH USUALLY DELAYED 5-12 DAYS. IF VICTIM SURVIV ES THIS PHASE, PRIMARY GI DISTURB USUALLY SUBSIDE. SECOND PHASE COMMONLY DEVELOPS W/IN 1-3 DAYS AFTER EXPOS. (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:576F,302C Melt/Freeze Pt:M.P/F.P Text:529F,276C Spec Gravity:5.0 pH:4.7 Solubility in Water:6.9% Appearance and Odor:ODORLESS, WHITE CRYSTALS OR POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POTASSIUM AND SODIUM: STRONG EXPLOSION ON IMPACT. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE CORROSIVE HYDROGEN CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FED, STATE & LOC REGS. FOR ASSIST CONT DISTRICT DIRECTOR OF ENVIRON PROT AGENCY. MERCURY-REGULATORY LEVEL: 0.2 MG/L (TCLP-40 CFR 261 APPENDIX II). MATLS WHICH CONTAIN ABOVE SUBSTANCE AT/AB OVE TCLP REGULATORY LEVEL MEET EPA (ING25) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.