J.T.BAKER CHEMICAL CO. -- SODIUM BISULFITE -- 6810-00-281-4255
===================== Product Identification ===================== Product ID:SODIUM BISULFITE MSDS Date:09/25/1989 FSC:6810 NIIN:00-281-4255 === Responsible Party === Company Name:J.T.BAKER CHEMICAL CO. Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151 CAGE:DO870 === Contractor Identification === Company Name:J.T.BAKER CHEMICAL CO. Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Phone:201-859-2151 CAGE:DO870 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BISULFITE (SASA III) CAS:7631-90-5 RTECS #:VZ2000000 Fraction by Wt: 90- 100% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:2000 MG/KG LD50 ORAL RAT Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: SEVERE IRRITATION OR BURNS TO SKIN AND EYES. INGESTION MAY RESULT IN ALLERGIC REACTIONS, AND COULD ALSO BE FATAL. Explanation of Carcinogenicity:SODIUM BISULFITE IS NOT LISTED AS A CARCINOGEN BY NTP, IARC, OR OSHA. Effects of Overexposure:SEVERE IRRITATION OR BURNING OF SKIN OR EYES. Medical Cond Aggravated by Exposure:ASTHMA ======================= First Aid Measures ======================= First Aid:INGESTION: INDUCE VOMITING IMMEDIATELY. CALL DOCTOR. INHALATION: GET FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. SKIN: FLUSH WITH WATER. WASH WITH PLENTY OF SOAP AND WATER. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SEE DOCTOR. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY Fire Fighting Procedures:WEAR PROTECTIVE EQUIPMENT AND FULL SCBA OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE. COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SCBA AND FULL PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. KEEP CONTAINERS CLOSED. Other Precautions:AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID BREATHING DUST. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXISTS. IF AIRBORNE CONCENTRATION IS HIGH, A DUST/MIST RESPIRATOR IS RECOMMENDED. IF CONCENTRATION EXCEEDS CAPACITY OF RESPIRATOR, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. Ventilation:USE LOCAL OR GENERAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Protective Gloves:PVC GLOVES. Eye Protection:SAFETY GOGGLES. Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE FROM PROLONGED OR REPEATED CONTACT. EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Spec Gravity:1.48 Solubility in Water:APPRECIABLE Appearance and Odor:WHITE POWDER, SULFUR DIOXIDE ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:OXIDES OF SULFUR, OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD ANY PRODUCT (INCLUDING ANY RETAINED MATERIALS OF USE), DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.