FISHER SCIENTIFIC -- VANADIUM REFERENCE STANDARD SOLUTION, SV15500 -- 6810-00N074326
===================== Product Identification ===================== Product ID:VANADIUM REFERENCE STANDARD SOLUTION, SV15500 MSDS Date:03/04/1996 FSC:6810 NIIN:00N074326 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:VANADIUM PENTOXIDE (SARA 302) (CERCLA) CAS:1314-62-1 RTECS #:YW2450000 Fraction by Wt: 0.18% OSHA PEL:0.5 MG/M3, C ACGIH TLV:0.05 MG/M3 RDUST EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYDROGEN CHLORIDE; (HYDROCHLORIC ACID) (SARA 302/313) (CERCLA) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 5.6% OSHA PEL:5 PPM, C ACGIH TLV:5 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER. LD50:(ORAL,RAT) 90 ML/KG. CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 94.22% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MATLS TO AVOID:HYDROXIDE, CALCIUM CARBIDE, CALCIUM PHOSPHIDE, CESIUM ACETYLENE CARBIDE, CESIUM CARBIDE, (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:CHLOROSULFONIC ACID, 1,1-DIFLUOROETHYLENE, ETHYLENE DIAMINE, ETHYLENEIMINE, FLUORINE, LITHIUM SILICIDE, (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:MAGNESIUM BORIDE, MERCURIC SULFATE, OLEUM, PERCHLORIC ACID, POTASSIUM PERMANGANATE, B-PROPIOLACTONE, (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:PROPYLENE OXIDE, RUBIDUM, ACETYLENE CARBIDE, RUBIDUM CARBIDE, SILVER PERCHLORATE & CARBON TETRACHLORIDE, (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:SODIUM, SODIUM HYDROXIDE, SULFURIC ACID, URANIUM PHOSPHIDE, VINYL ACETATE. SUBSTANCE POLYMERIZES ON CONT (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:W/ALDEHYDES OR EPOXIDES. RTECS #:9999999ZZ Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 3. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:MAY CAUSE IRREVERSIBLE INJURY. VAP/MIST MAY CAUSE IRRIT & SEV BURNS. CONT W/LIQ IS CORR & CAUSES SEV BURNS. SKIN:CONT W/LIQ IS CORR & CAUSES SEV BURNS & ULCERATION. INGEST:MAY CAUSE CIRCULAT ORY SYS FAILURE. CAUSES SEV DIGEST TRACT BURNS W/ABDOM PAIN, VOMIT & POSS DEATH. MAY CAUSE CORR & PERM (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:TISS DESTRUCT OF ESOPHAGUS & DIGEST TRACT. INHAL:CAUSES SEV IRRIT OF UPPER RESP TRACT W/COUGH, BURNS, BRTHG DFCLTY & POSS COMA. MAY CAUSE PULM EDEMA & SEV RESP DISTURBS. CHRONIC:PRLNG/RPTD SK IN CONT MAY CAUSE DERM. RPTD EXPOS MAY CAUSE EROSION OF TEETH. HYDROGEN CHLORIDE:POSS OCCUP CARCIN AS NICKEL (MFR). Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLSD. SKIN:GET MED AID IMMED. IMMED FLUSH W/PLENTY OF S OAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAM CLTHG & SHOES. DESTROY CONTAM SHOES. INGEST:DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:SUBSTANCE IS NONFLAMMABLE, USE AGENT MOST APPROPRIATE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILL USING ABSORB, NON-COMBUST MATL SUCH AS EARTH, SAND/VERMICULITE. HYDROCHLORIC ACID WILL NEUT SOIL CARBONATE-BASED COMPONENTS. HYDROGEN CHLORIDE IS LISTED AS HAZ AIR POLLUTANT (HAP), HAZ SU BSTANCE UNDER CLEAN WATER ACT & IS (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. USE W/ADEQUATE VENTILATION. DO NOT GET ON SKIN OR IN EYES. Other Precautions:DANGER! CORROSIVE. CAUSES SKIN & EYE BURNS. CAUSES DIGESTIVE TRACT BURNS, CAUSES RESPIRATORY TRACT BURNS. DO NOT INGEST OR INHALE. USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CON TROLS, PERSONAL PROTECTION SECTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW PELS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 10) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . WEAR APPROP PROT CLTHG TO PREVENT SKIN EXPOS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING & WASH BEFORE REUSE. Supplemental Safety and Health SPILL PROC:CONSIDERED HIGHLY HAZ BY OSHA. VANADIUM PENTOXIDE IS LISTED AS HAZ SUBSTANCE UNDER CLEAN WATER ACT. FIRST AID PROC:AID IMMED. INHAL:REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MED AID. NOTES TO MD:TREAT SYMPTOMATICALLY & SUPPORTIVELY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:14 @ 20C Vapor Density:0.7 Spec Gravity:1 Evaporation Rate & Reference:1 (ETHER=1) Solubility in Water:COMPLETELY SOLUBLE Appearance and Odor:GREEN-YELLOW LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROCHLORIC ACID IS INCOMPAT W/ACETATE, ACETIC ANHYDRIDE, ALCOHOLS & HYDROGEN CYANIDE, 2-AMINOETHANOL, AMMONIUM (ING 4) Stability Condition to Avoid:INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:HYDROGEN CHLORIDE, HYDROGEN GAS, VANADIUM OXIDE (VO*X) GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT W/FEDERAL, STATE & LOCAL REGULATIONS. NOT LISTED AS A MATERIAL BANNED FROM LAND DISPOSAL ACCORDING TO RCRA. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.