E.I. DUPONT DE NEMOURS & CO (INC) -- SUVA HP62 (R404A) -- -
===================== Product Identification ===================== Product ID:SUVA HP62 (R404A) MSDS Date:03/24/1999 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:E.I. DUPONT DE NEMOURS & CO (INC) Address:1001 MARKET STREET City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-9442 Emergency Phone Num:800-441-3637 Resp. Party Other MSDS Num.:DU005612 Preparer's Name:DUPONT CHEMICALS Chemtrec Ind/Phone:(800)424-9300 CAGE:18873 === Contractor Identification === Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:PENTAFLUOROETHANE CAS:354-33-6 = Wt:44. Other REC Limits:NONE RECOMMENDED Ingred Name:1,1,1-TRIFLUOROETHANE (HFC-143A) CAS:420-46-2 RTECS #:KJ4110000 = Wt:52. Other REC Limits:NONE RECOMMENDED Ingred Name:1,1,1,2-TETRAFLUOROETHANE (HFC-134A) CAS:811-97-2 = Wt:4. Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION OF HIGH CONCENTRATIONS OF VAPOR IS HARMFUL & MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. INTENTIONAL MISUSE OR DELIBERATE INHALATION MAY CAUSE DEATH WITHOUT WARNING. VAPOR RED UCES OXYGEN AVAILABLE FOR BREATHING & IS HEAVIER THAN AIR. LIQUID CONTACT CAN CAUSE FROSTBITE. Explanation of Carcinogenicity:PER MSDS: CARCINOGENICITY: NONE OF COMPONENTS PRESENT IN MATERIAL AT CONCENTRATIONS EQUAL TO/>0.1% LISTED BY IARC/NTP/OSHA/ACGIH AS CARCINOGEN. Effects of Overexposure:OVEREXPOSURE TO VAPORS BY INHALATION MAY INCLUDE TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANESTHETIC EFFECTS SUCH AS DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION & LOSS OF CONSCIOUSNESS. HIGHER EXPO SURES TO VAPORS MAY CAUSE TEMPORARY ALTERATION OF HEART'S ELECTRICAL ACTIVITY WITH IRREGULAR PULSE, PALPITATIONS OR INADEQUATE CIRCULATION; FATALITY FROM GROSS OVEREXPOSURE. CONTACT WITH LIQUID MAY CA USE FROSTBITE. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF INCREASED EXPOSURES. ======================= First Aid Measures ======================= First Aid:INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. KEEP PERSON CALM. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT GIVE OXYGEN. CALL PHYSICIAN. SKIN: FLUSH WITH LUKEWARM WATER. DO NOT USE HOT WATER. IF FROSTBITE HAS OCCURRED CALL PHSYICIAN. EYE:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15MINS. CALL PHYSICIAN. INGESTION: NOT PROBABLE ROUTE, HOWEVER IN CASE OF ACCIDENTA L INGESTION CALL PHYSICIAN. NOTE TO PHYSICIAN: CATECHOLAMINES SUCH AS ADRENALINE & OTHER COMPOUNDS HAVING SIMILAR EFFECTS SHOULD BE RESERVED FOR EMERGENCIES & THEN ONLY USED WITH SPECIAL CAUTION. ===================== Fire Fighting Measures ===================== Flash Point:WILL NOT BURN Autoignition Temp:Autoignition Temp Text:UNK Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA. Fire Fighting Procedures:COOL CYLINDER WITH WATER SPRAY OR FOG. SELF-CONTAINED BREATHING APPRATUS (SCBA) IS REQUIRED IF CYLINDERS RUPTURE & CONTENTS ARE RELEASED UNDER FIRE CONDITIONS. WATER RUNOFF SHOULD BE CONTAINED & NEUTR ALIZED PRIOR TO RELEASE. Unusual Fire/Explosion Hazard:NOT FLAMMABLE UP TO 212F & ATMOSPHERIC PRESSURE. BUT MIXTURES IN HIGH CONCENTRATIONS OF AIR AT ELEVATED TEMPERATURE CAN BECOME COMBUSTIBLE AT AMBIENT TEMPERATURE. AS TEMPERATURE IS INCREASED, LOWER PR ESSURE (STILL > ATMOSPHERIC) CAN CREATE SAME EFFECT. THEREFORE PRODUCT SHOULD NOT BE MIXED WITH AIR UNDER PRESSURE. ================== Accidental Release Measures ================== Spill Release Procedures:REVIEW FIREFIGHTING MEASURES & HANDLING/STORAGE SECTIONS BEFORE CLEANUP. USE APPROPRIATE PPE DURING CLEANUP. VENTILATE AREA WITH FORCED VENTILATION, ESPECIALLY IN LOW OR ENCLOSED AREAS WHERE VAPORS CA N COLLECT. REMOVE OPEN FLAMES. USE SELF-CONTAINED BREATHING APPARATUS (SCBA) FOR LARGE SPILLS OR RELEASES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING VAPOR. AVOID LIQUID CONTACT WITH EYES & SKIN. USE WITH SUFFICIENT VENTILATION. CONTACT WITH CHLORINE OR OTHER STRONG OXIDIZERS SHOULD BE AVOIDED. STORE IN CLEAN, DRY AREA. DO NOT HEAT ABOVE 52C (125F). Other Precautions:CONTACT OF WELDING OR SOLDERING TORCH FLAMES WITH HIGH CONCENTRATION OF REFRIGERANT CAN RESULT IN VISIBLE CHANGES IN SIZE & COLOR OF TORCH FLAMES. THIS EFFECT WILL ONLY OCCUR IN CONCENTRATIONS WELL AB OVE RECOMMENDED EXPOSURE LIMIT. THEREFORE STOP ALL WORK & VENTILATE TO DISPERSE VAPORS BEFORE USING OPEN FLAMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITONS NO RESPIRATORY PROTECTION IS REQUIRED WHEN USING PRODUCT. SELF-CONTAINED BREATHING APPARATUS REQUIRED IF LARGE RELEASES OCCURS. Ventilation:LOCAL EXHAUST SHOULD BE USED IF LARGE AMOUNTS ARE RELEASED. MECHANICAL VENTILATION SHOULD BE USED IN LOW OR ENCLOSED PLACES. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:CHEM SPLASH GOGGLES. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:=-46.5C, -52.F Vapor Pres:182 PSIA @ 77F Vapor Density:NP Spec Gravity:1.05 @25C pH:NOT PROVIDED Viscosity:NOT PROVIDED Evaporation Rate & Reference:>1, CL4=1. Solubility in Water:NOT DETERMINED. Appearance and Odor:SLIGHT ETHEREAL ODOR, LIQUEFIED GAS, CLEAR, COLORLESS. Percent Volatiles by Volume:100 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACTIVE METALS, ALKALI OR ALKALINE EARTH METALS-POWDERED AL, ZN, BE, ETC. Stability Condition to Avoid:AVOID OPEN FLAMES & HIGH TEMPERATURES. Hazardous Decomposition Products:CAN DECOMPOSE BY HIGH TEMPERATURE (OPN FLAMES/GLOWING METAL SURFACES/ETC) FORMING HYDROFLUORIC ACID & POSSIBLY CARBONYL FLUORIDE. THESE MATERIALS ARE TOXIC & IRRITATING. CONTACT SHOULD BE AVOIDED. =================== Toxicological Information =================== Toxicological Information:BLEND IS UNTESTED. FOR HFC-125: INHALATION 4 HR ALC: > 709,000 PPM IN RATS. NO OBSERVED EFFECT LEVEL: 50,000 PPM FOR HFC-134A: INHALATION 4 HR LC50: 567,000 PPM IN RATS, LOWEST OBSERVED ADVERSE EFFECT LEVEL: 75,000 PPM. FOR HFC-143A: INHALATION 4 HR LC50: >540,000 PPM IN RATS. ===================== Ecological Information ===================== Ecological:AQUATIC TOXICITY: HFC-143A, 96 HR LC50, RAINBOW TROUT: > 40 MG/L. HFC-134A: 48 HR EC50, DAPHNIA MAGNA: 980 MG/L, 96 HR LC50, RAINBOW TROUT: 450 MG/L. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH LOCAL, STATE AND FEDERAL REGULATIONS. RECLAIM BY DISTILLATION OR REMOVE TO PERMITTED WASTE DISPOSAL FACILITY. =================== MSDS Transport Information =================== Transport Information:DOT INFORMATION: LIQUEFIED GAS, N.O.S. (PENTAFLUOROETHANE & TETRAFLUOROETHANE), 2.2, UN3163, NONFLAMMABLE GAS LABEL. ===================== Regulatory Information ===================== SARA Title III Information:SARA EHS & TOXIC: NO, SECTION 311/312 CLASSIFICATION: PRESSURE. Federal Regulatory Information:CERCLA HAZARDOUS MATERIAL: NO State Regulatory Information:NOT PROVIDED Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.