FISHER SCIENTIFIC CHEMICAL DIV -- AMMONIUM NITRATE -- 6810-00F029901
===================== Product Identification ===================== Product ID:AMMONIUM NITRATE MSDS Date:02/25/1992 FSC:6810 NIIN:00F029901 === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL DIV Address:1 REAGENT LN City:FAIR LAWN State:NJ ZIP:07410-2802 Country:US Info Phone Num:201-796-7100/201-796-7523 Emergency Phone Num:201-796-7100/201-796-7523 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM NITRATE CAS:6484-52-2 RTECS #:BR9050000 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 2217 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT IRRITATION, METHEMOGLOBINEMIA, PULMONARY EDEMA & CHEMICAL PNEUMONITIS. SKIN: IRRITATION, BURNS & DERMATITIS. EYES: IRRITATION, BURNS & CONJUNCTIVITIS. INGESTION: MILD GAS TRIC IRRITATION, SYSTEMIC ACIDOSIS & METHEMOGLOBINEMIA W/CYANOSIS, ANEMIA, NEPHRITIS. MODERATELY TOXIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: SORE THROAT, COUGHING, DIFFICULT BREATHING, SEVERE LUNG CONGESTION, ACIDOSIS, ALLERGIC RESPONSE IN RESPIRATORY TRACT. SKIN/EYES: REDNESS & PAIN. INGESTION: ABDOMINAL SPASMS, NAUSEA, FAINTN ESS. POISONING MAY AFFECT THE BLOOD. (SEE SUPPLEMENTAL) ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. SKIN: REMOVE CONTAMINATED CLOTHING/SHOES. WASH W/SOAP & WAT ER OR MILD DETERGENT & PLENTY OF WATER FOR ABOUT 15-20 MINS. EYES: FLUSH W/PLENTY OF WATER OR NORMAL SALINE, LIFING UPPER & LOWER LIDS FOR ABOUT 15-20 MINS. (SEE SUPPLEMENTAL). ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER ONLY. NO DRY CHEMICAL, CO2 OR HALON. Fire Fighting Procedures:DON'T MOVE CARGO OR VEHICLE IF CARGO HAS BEEN EXPOSED TO HEAT. APPLY COOLING WATER TO SIDES OF CONTAINERS EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT. Unusual Fire/Explosion Hazard:USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES. IF THIS IS IMPOSSIBLE, WITHDRAW FROM AREA & LET FIRE BURN. DANGEROUS EXPLOSION HAZARD WHEN EXPOSED TO HEAT/FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP COMBUSTIBLES AWAY FROM SPILLED MATERIAL. DON'T TOUCH SPILL. STOP LEAK IF YOU CAN WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP ABSORBENT MATERIAL & PLACE INTO CONTAINERS FOR DISPOSAL. D IKE LARGE SPILLS. KEEP PEOPLE AWAY/DENYENTRY. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. STORE IN WELL-VENTILATED BUILDINGS OF NON-COMBUSTIBLE CONSTRUCTION & EQUIPPED W/AUTOMATIC SPRINKLERS. Other Precautions:FLOOR DRAINS & RECESSES SHOULD BE PLUGGED OR ELIMINATED TO PREVENT ENTRAPMENT OF FLOWING MOLTEN NITRATE DURING FIRE. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. MAY EXPLODE W/MIXTURE OF FUELS, FROM FRICT ION, HEAT OR CONTAMINATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED DUST/MIST RESPIRATOR OR PURIFYING W/HIGH EFFICIENCY PARTICULATE FILTER, TYPE C SUPPLIED-AIR OPERATED IN PRESSURE-DEMAND/POSITIVE PRESSURE/CONTINUOUS-FLOW MODE, SELF-CONTAINED B REATHING APPARATUS W/FULL FACEPIECE. Ventilation:LOCAL EXHAUST. EQUIPMENT MUST BE EXPLOSION PROOF. Protective Gloves:PROTECTIVE Eye Protection:SPLASH-PROOF, DUST-RESISTANT GOGGLES Other Protective Equipment:EYE WASH FOUNTAIN Supplemental Safety and Health CHRONIC/ACUTE INGESTION: RARELY INORGANIC NITRATES MAY BE CONVERTED TO NITRITES BY NITRATE-REDUCING BACTERIA IN DIGESTIVE TRACT, CAUSING METHEMOGLOBINEMIA. FIRST AID: TREAT SYMPTOMATICALLY/SUPPORTIVEL Y. IF CONSCIOUS, GIVE PLENTY OF WATER/MILK TO DILUTE. ANTIDOTE: METHYLENE BLUE 1%, 0.1 ML/KG INTRAVENOUSLY OVER 10 MINS. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:410F/210C Melt/Freeze Pt:M.P/F.P Text:338F/170C Spec Gravity:1.725 pH:5.4 Solubility in Water:118% @ 0C Appearance and Odor:COLORLESS TO WHITE, DELIQUESCENT, RHOMBIC CRYSTALS OR GRANULES, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO STRONG ALKALIES, ACIDS, METALS (POWDERED/SALTS), ORANIC MATERIALS, REDUCING AGENTS, SODIUM, ACETIC ACID, POTASSIUM Stability Condition to Avoid:HEAT, FLAME Hazardous Decomposition Products:TOXIC & CORROSIVE FUMES OF AMMONIA & TOXIC OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. EPA HAZARDOUS WASTE NUMBERS. D001 & D003. UN 1942. 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