U S AIRGAS INC. -- ACETYLENE -- 6830-00-286-5434
===================== Product Identification ===================== Product ID:ACETYLENE MSDS Date:05/01/1990 FSC:6830 NIIN:00-286-5434 === Responsible Party === Company Name:U S AIRGAS INC. Address:100 MATSONFORD ROAD SUITE 550 City:RADNOR State:PA ZIP:19087 Country:US Info Phone Num:215-687-5253 Emergency Phone Num:215-687-1052 CAGE:0MN39 === Contractor Identification === Company Name:AIRGAS INC Address:100 MATSONFORD RD SUITE 550 Box:City:WAYNE State:PA ZIP:19087 Country:US Phone:215-687-5253 CAGE:0MN39 ============= Composition/Information on Ingredients ============= Ingred Name:ACETYLENE CAS:74-86-2 RTECS #:AO9600000 Fraction by Wt: 100% ACGIH TLV:ASPHYXIANT; 9495 ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACETYLENE IS A SIMPLE ASPHYXIANT. MAINTAIN OXYGEN LEVELS OF >18 MOLAR PERCENT. Explanation of Carcinogenicity:NOT LISTED BY IARC, NTP OR OSHA AS A CARDINOGEN OR POTENTIAL CARCINOGEN. Effects of Overexposure:ACETYLENE IS A SIMPLE ASPHYXIANT. LOW CONCENTRATION MAY CAUSE INTOXICATION. HIGHER CONCENTRATION CAN CAUSE UNCONSCIOUSNESS. AS A NARCOTIC GAS OR INTOXICANT CAUSES HYPERCAPNIA (INCREASED CO2 IN BLOOD). Medical Cond Aggravated by Exposure:PERSONS IN ILL HEALTH WHERE SUCH ILLNESS WOULD BE AGGRAVATED BY EXPOSURE TO ACETYLENE SHOULD NOT BE ALLOWED TO WORK WITH OR HANDLE THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO ACETYLENE.RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS & BE AWARE OF EXTREME FIRE & EXPLOSION HAZAR D.REMOVE FROM EXPOSURE QUICKLY.PROVIDE CPR/OXYGEN IF UNCONSCIOUS.TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:FLAMMABLE GAS Autoignition Temp:Autoignition Temp Text:565F Lower Limits:2.2 Upper Limits:80 - 85 Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY. Fire Fighting Procedures:IF POSSIBLE, STOP FLOW OF GAS. USE WATER TO COOL SURROUNDING CONTAINERS. KEEP PERSONNEL AWAY SINCE HEATED OR BURNING CYLINDERS CAN RUPTURE VIOLENTLY. Unusual Fire/Explosion Hazard:ACETYLENE IS SPONTANEOUSLY COMBUSTIBLE IN AIR AT PRESSURE >30PSIA. FIRES WHICH HAVE BEEN EXTINGUISHED W/O STOPPING FLOW OF GAS CAN EASILY REIGNITE & EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. USE APPROPRIATE PROTECTIVE EQUIPMENT. REMOVE ALL SOURCES OF IGNITION. AVOID ENTERING AREA OF FLAMMABLE ATMOSPHERE. IF LEAK IS IN USER'S EQUIPMENT, PURGE PIPING WITH AN INERT GAS. IF LE AK IS IN CONTAINER/VALVE, CONTACT NEAREST SUPPLIER Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL-VENTILATED AREA.KEEP CYLINDERS UPRIGHT & FIRMLY SECURED. Other Precautions:USE "FIRST IN-FIRST OUT" INVENTORY SYSTEM. POST "NO SMOKING/OPEN FLAMES" SIGN IN THE STORAGE AREA. THERE SHOULD BE NO SOURCES OF IGNITION IN STORAGE/USE AREA. DO NOT ALLOW THE TEMPERATURE WHERE CYLIND ERS ARE STORED TO EXCEED 130F (54C). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:POSITIVE PRESSURE AIR LINE WITH MASK OR SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE. Ventilation:LOCAL & MECHANICAL Protective Gloves:PVC OR RUBBER Eye Protection:SAFETY GLASSES/GOGGLES Other Protective Equipment:SAFETY SHOES, EMERGENCY SHOWER Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:G2 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:-119F,-84C Melt/Freeze Pt:M.P/F.P Text:-113F,-81C Vapor Pres:645 PSIA Evaporation Rate & Reference:N/A. Solubility in Water:SOLUBLE Appearance and Odor:PURE ACETYLENE IS COLORLESS-ETHEREAL ODOR.COMMERCIAL ACETYLENE GARLIC-LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO OXYGEN & OTHER OXIDIZERS INCLUDING ALL HALOGENS & HALOGEN COMPOUNDS. FORMS EXPLOSIVE METAL ACETYLIDES Stability Condition to Avoid:DO NOT ALLOW FREE GAS TP EXCEED 30 PSIA. DO NOT EXPOSE CYLINDERS TO SUDDEN SHOCK OR SOURCES OF HEAT. Hazardous Decomposition Products:CARBON & HYDROGEN Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF WASTE OR UNUSED QUANTITIES. RETURN IN THE SHIPPING CONTAINER PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED & VALVE PROTECTION CAP IN PLACE TO YOUR SUPPLIER OR CALL THE EMERGENCY TELEPHONE NUMBER. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.