MALLINCKRODT INC., SCIENCE PRODUCTS DIVISION -- FERRIC CHLORIDE -- 6810-00-299-8503
===================== Product Identification ===================== Product ID:FERRIC CHLORIDE MSDS Date:08/07/1985 FSC:6810 NIIN:00-299-8503 === Responsible Party === Company Name:MALLINCKRODT INC., SCIENCE PRODUCTS DIVISION Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:606-987-7000 Emergency Phone Num:606-987-7000/314-982-5000 Preparer's Name:SSH CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:FERRIC (III) CHLORIDE HEXAHYDRATE CAS:10025-77-1 RTECS #:NO5425000 Fraction by Wt: >98% Other REC Limits:NONE DETERMINED OSHA PEL:1 MG/M3 (FE) ACGIH TLV:1 MG/M3 (FE); 8990 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 1872 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT, EYES & SKIN. INHALATION MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION & EDEMA OF THE LARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY EDEMA. Effects of Overexposure:SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA & VOMITING. CAUSES SEVERE EYE IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED. ======================= First Aid Measures ======================= First Aid:INHALE-REMOVE TO FRESH AIR. PERFORM CPR OR GIVE OXYGEN IF BREATHING IS DIFFICULT. SEE DOCTOR. INGEST-IMMEDIATELY INDUCE VOMIT BY GIVING 2 GLASSES OF WATER. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. SEE DO CTOR IMMEDIATELY. SKIN/EYES-FLUSH IMMEDIATELY WITH LARGE QUANTY OF WATER FOR 15 MIN.REMOVE CONTAMINATED CLOTHES. SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINQUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS, COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE SPILL AREA. CLEAN UP PERSONS NEED PROTECTIVE CLOTHESG/RESPIRATORS FROM DUST. PICK UP SPILL & PLACE IN A SUITABLE CONTAINER FOR RECLAMATION/DISPOSAL IN A WAY THAT DOES NOT GENERATE DUST; NEUT RALIZE SMALL QUANTY WITH SODA ASH & FLUSH TO SEWER Neutralizing Agent:SODA ASH. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTNRS IN A COOL, DRY, VENTILATED PLACE. PROTECT AGAINST PHYSICAL DAMAGE. KEEP AWAY FROM MOISTURE & OXIDIZING MATERIALS. Other Precautions:AVOID BREATHING DUST. USE WITH ADEQUATE VENTILATION. KEEP CONTAINRS CLOSED. WASH THOROUGHLY AFTER HANDLING. AVOID SKIN, EYES & CLOTHING CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST/MIST RESPIRATOR. Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV. Protective Gloves:IMPERVIOUS Eye Protection:SAFETY/CHEMICAL GOGGLES Other Protective Equipment:FULL PROTECTIVE CLOTHING, SAFETY SHOWER, EYE WASH STATION. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING THIS MATERIAL. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:DECOM @300C Melt/Freeze Pt:M.P/F.P Text:DECOM @306C Spec Gravity:1.82 Solubility in Water:APPRECIABLE Appearance and Odor:YELLOW BROWN DELIQUESCENT CRYSTALS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS; METALS, ALYL CHLORIDE, SOD-POT ALLOY. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, EMITS HYDROGEN CHLORIDE FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DISPOSD AS HAZ WASTE IN A RCRA APPROVED WASTE DISPOSAL FACILITY. COMPLY WITH LOCAL, STATE & FEDERAL REGULATIONS; SMALL QUANTITIES CAN BE NEUTRALIZED W/S ODA ASH & FLUSHED TO SEWER; CWA/CERCLA RQ: 1000LBS Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.