FISHER SCIENTIFIC CO -- 9967, VANADIUM REFERENCE STANDARD SOLUTION(SUPDAT) -- 6810-00N056722 
=====================  Product Identification  =====================

Product ID:9967, VANADIUM REFERENCE STANDARD SOLUTION(SUPDAT)
MSDS Date:04/12/1991
FSC:6810
NIIN:00N056722
=== Responsible Party ===
Company Name:FISHER SCIENTIFIC CO
Address:1 REAGENT LN
City:FAIR LAWN
State:NJ
ZIP:07410-2802
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company Name:FISHER SCIENTIFIC CO.  CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464

=============  Composition/Information on Ingredients  =============

Ingred Name:HYDROGEN CHLORIDE  (HYDROCHLORIC ACID) (SARA 302/313)
    (CERCLA)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 6.1%
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:VANADIUM PENTOXIDE (SARA 302) (CERCLA)
CAS:1314-62-1
RTECS #:YW2450000
Fraction by Wt: 0.16%
OSHA PEL:C,0.5 MG/M3
ACGIH TLV:0.05 MG/M3 RDUST
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 93.7%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPDAT:EXTING USING AGENTS INDICATED:DO NOT USE WATER
    DIRECTLY ON MATL. IF LG AMTS OF COMBUST MATLS ARE INVOLVED,(ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4:USE WATER SPRAY/FOG IN FLOODING AMTS. USE WATER SPRAY
    TO ABSORB CORR VAPS. COOL CNTNRS W/FLOODING AMTS OF (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:WATER FROM AS FAR A DIST AS POSS. AVOID BREATHING
    CORR VAPORS; KEEP UPWIND.
RTECS #:9999999ZZ

Ingred Name:MATLS TO AVOID:SPECIFIC INFORMATION CONTACT NEHC .
RTECS #:9999999ZZ

Ingred Name:EFTS OF OVEREXP:INFLAMM, ULCERATION, NECROSIS & CHEM BURNS.
    SHOCK SYMPS MAY DEVELOP INCL PARID PULSE, SWEAT & (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:COLLAPSE. PHOTOSENSIT RXNS MAY OCCUR IN PERSONS
    PREVIOUSLY EXPOD. CONT W/COMPRESSED GAS MAY CAUSE (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:FROSTBITE. EYE:CONT MAY CAUSE SEV IRRIT, CONJ,
    CORNEAL NECROSIS & BURNS W/IMPAIRMENT/PERM LOSS OF VISION. (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:DROP OF HYDROCHLORIC ACID SPLASHED IN EYE & IMMED
    WASHED OUT HAS PRDCED WHITE COAGULATION OF CORNEAL & (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:CONJ EPITHELIUM. ANIMALS EXPOS TO VAP CONCS OF 1350
    PPM FOR 1 1/2 HRS SHOWED CLOUDING OF CORNEA & 300 PPM(ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:FOR 6 HRS SHOWED SLIGHT EROSION OF CORNEAL
    EPITHELIUM, CONT W/COMPRESSED GAS MAY CAUSE FROSTBITE. INGEST:(ING
    4)
RTECS #:9999999ZZ

Ingred Name:ING 13:ACID MAY CAUSE BURNS OF MOUTH, THROAT, ESOPHAGUS &
    STOM W/CONSEQUENT PAIN, UNEASINESS, NAUS, SALIVATION.(ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:VOMIT, DIARR, CHILLS, SHOCK & INTENSE THRIST,
    NEPHRITIS. FEVER & PERFORATION OF INTESTINAL TRACT & (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15:CIRCULATORY COLLAPSE MAY OCCUR. DEATH MAY BE DUE TO
    ESOPHAGEAL/GASTRIC NECROSIS. CHRONIC:INHAL:RPTD OR (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16:PRLNGD EXPOS MAY CAUSE EROSION & DISCOLORATION OF
    EXPOS TEETH. CHRONIC BRONCH & GASTRITIS. SKIN:RPTD OR (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17:PRLNGD CONT W/VAPS/DILUTE SOLNS MAY CAUSE DERM.
    PHOTOSENSIT MAY OCCUR. EYE:ANIMALS EXPOS TO VAP @ 100PPM(ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18:FOR 6 HRS DAILY FOR 50 DAYS SHOWED ONLY SLIGHT
    UNREST & IRRIT OF EYES, BUT NO OCULAR INJURY. EFTS ARE (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:DEPENDENT UPON CONC & DURATION OF EXPOS. CONJ/EFTS
    SIMILAR TO THOSE FOR ACUTE EXPOS MAY OCCUR.
RTECS #:9999999ZZ

Ingred Name:OTHER PROT EQUIP:SKIN CONTACT WITH THIS SUBSTANCE.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:100 FOLD TO RENDER IT HARMLESS TO TISSUES.
    MAINTAIN AIRWAY & TREAT SHOCK (DREISBACH, HANDBOOK OF (ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22:POISONING, 12TH ED.). GET MED ATTN IMMED. IF VOMIT
    OCCURS, KEEP HEAD BELOW HIPS TO HELP PVNT ASPIR. (ING 24)
RTECS #:9999999ZZ

Ingred Name:ING 23:ANTIDOTE:NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY
    AND SUPPORTIVELY.
RTECS #:9999999ZZ

Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:GAS/FUMES @ LEVELS OF 5-35
    PPM MAY CAUSE IRRIT & BURNING OF THROAT, COUGH & CHOKING; 50-100
    PPM MAY BE BARELY TOLERABLE FOR 1 HR. HIGH LEVELS MAY CAUSE INFLAMM
    & OCCASNLY ULCERATION OF NOS E, THROAT/LARYNX, BRONCH, PNEUM,
    PALPITATIONS & HDCH. HIGHER CONCS MAY CAUSE NECROSIS OF TRACHEA, &
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:BRONCH EPITHELIUM, NASOSEPTAL
    PERFORATION, ATELECTASIS, EMPHYSEMA, DMG TO PULM BLOOD VESS &
    LESIONS OF LIVER & OTHER ORGANS. DEATH MAY BE DUE TO LARYNGEAL
    SPASM, BRONCHOPNEUM/PULM EDEMA. 1300 -2000 PPM MAY BE DANGEROUS
    EVEN ON BRIEF EXPOS. REPROD EFTS RPTD IN ANIMALS. SKIN:MAY CAUSE
    SEV IRRITATION,(ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE OXYG/ARTF
    RESP) . EYES:IMMED FLUSH W/POTABLE WATER FOR @ LST 15 MIN, SEEK
    ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMTS OF WATER. CALL MD (F
    P N). INGEST:DO NOT USE GASTRIC LAVAGE/EMESIS. DILUTE ACID IMMED BY
    DRINKING LG QTYS OF WATER/MILK. IF VOMIT PERSISTS, ADMIN FLUIDS
    REPEATEDLY. INGESTED ACID MUST BE DILUTED APPROXIMATELY (ING 22)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:DRY CHEM, CO*2, WATER SPRAY/REGULAR FOAM. LGR
    FIRES, USE WATER SPRAY, FOG/REGULAR FOAM (1990 EMER RESPONSE
    (SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
    HEAT OR FLAME.

==================  Accidental Release Measures  ==================

Spill Release Procedures:OCCUPATIONAL SPILL:COVER WITH SODA ASH. SCOOP
    UP AND PLACE IN A SUITABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
    EXPOSURE OF CONCERN .
Ventilation:PROVIDE LOCAL EXHAUST/PROCESS ENCLOSURE VENT TO MEET
    PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 25)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
    APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT POSSIBILITY OF (ING
    21)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:1000 PPM. EXTING MEDIA:GUIDEBOOK, DOT P 5800.5).
    MOVE CNTNR FROM FIRE AREA IF CAN BE DONE W/OUT RISK. APPLY COOLING
    WATER TO SIDES OF CNTNRS THAT ARE EXPOS TO FLAMES UNTIL WELL  AFTER
    FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS (1990 EMER RESPONSE
    GUIDEBOOK, DOT P 5800.5, GUIDE PAGE 601. (ING 4)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Pres:14 @ 20C
Vapor Density:0.7 (H*2O)
Spec Gravity:1.0
Evaporation Rate & Reference:>1 (ETHER =1)
Solubility in Water:COMPLETELY
Appearance and Odor:GREEN-YELLOW LIQUID.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ACETIC ANHYDROIDE, ALCOHOLIC HYDROGEN CYANIDE, ALUMINUM,
    ALUMINIUM-TITANIUM ALLOYS, 2-AMINOETHANOL. FOR MORE (ING 7)
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
    PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
    CORROSIVE HYDROGEN CHLORIDE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
    REGULATIONS .

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.