SIGMA CHEMICAL CO -- NEUTRAL RED PURIFIED, N7005 -- 6810-00N093260
===================== Product Identification ===================== Product ID:NEUTRAL RED PURIFIED, N7005 MSDS Date:01/01/1999 FSC:6810 NIIN:00N093260 Status Code:A === Responsible Party === Company Name:SIGMA CHEMICAL CO Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Info Phone Num:314-771-5765 Emergency Phone Num:314-771-5765 CAGE:21076 === Contractor Identification === Company Name:SIGMA CHEMICAL COMPANY Address:3050 SPRUCE ST Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Phone:314-771-5765 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:NEUTRAL RED; (NEUTRAL RED PURIFIED) CAS:553-24-2 RTECS #:SG1400000 = Wt:100. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN. MAY CAUSE IRRITATION. CHRONIC: LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. INHALATI ON: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIO US. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. POSSIBLE MUTAGEN. HARMFUL SOLID. KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves:RUBBER GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=290.C, 554.F M.P/F.P Text:DEC Appearance and Odor:BLACK OR VERY DARK-GREEN POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS: TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES, HYDROGEN CHLORIDE GAS. =================== Toxicological Information =================== Toxicological Information:TO BEST OF MFR'S KNOWLEDGE, CHEMICAL, PHYSICAL, & TOX PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. RTECS #: SG1400000 PHENAZINE, 3-AMINO-7-(DIMETHYLAMINO)-2-METHYL-, HYDROCHLORIDE. TOX DATA: IVN- RAT LD50:112 MG/KG FEPRA7 10,337,1951 IPR-MUS LD50:432 MG/KG ZYZAEU 25,356,1990 IVN-MUS LD50:142 MG/KG FEPRA7 10,337,1951 IVN-RBT LD50:96600 UG/KG SMBUA9, 96,1951. TARGET ORGAN DATA: BEHAVIORAL (CONVU LSIONS/EFTS ON SEIZURE THRESHOLD). CARDIAC (OTHER CHANGES) LUNGS, THORAX/RESP (RESP STIMULATION) (OTHER CHANGES). ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) (SARA TITLE III ) ===================== Ecological Information ===================== Ecological:DATA NOT YET AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ===================== Regulatory Information ===================== SARA Title III Information:NP- TOXIC INFO: DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. Federal Regulatory Information:EUROPEAN INFORMATION: HARMFUL R 20/21/22 HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. R 40 POSSIBLE RISK OF IRREVERSIBLE EFFECTS. S 36 WEAR SUITABLE PROTECTIVE CLOTHING. State Regulatory Information:REVIEWS, STANDARDS, AND REGULATIONS: OEL=MAK. NOHS 1974: HZD M1598; NIS 5; TNF 420; NOS 5; TNE 694. NOES 1983: HZD M1598; NIS 13; TNF 746; NOS 12; TNE 23740; TFE 19202. EPA GENETOX PROGRAM 1988, POSIT IVE: HISTIDINE REVERSION-AMES TEST. EPA GENETOX PROGRAM 1988, NEGATIVE: N CRASSA-ANEUPLOIDY. EPA GENETOX PROGRAM 1988, INCONCLUSIVE: E COLI POLA WITHOUT S 9. EPA GENETOX PROGRAM 1988, INCONCLUSIVE: D MELANOGASTER SEX-LINKED LETHAL. EPA TSCA SECTION 8 (B) CHEMICAL INVENTORY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.