SIGMA CHEMICAL CO -- G6138, A-D(+)-GLUCOSE ANHYDROUS (SUPDAT)  -- 6550-00N092588
<pre>=====================  Product Identification  =====================

Product ID:G6138, A-D(+)-GLUCOSE ANHYDROUS (SUPDAT)
MSDS Date:01/01/1999
FSC:6550
NIIN:00N092588
Status Code:A
=== Responsible Party ===
Company Name:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company Name:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076

=============  Composition/Information on Ingredients  =============

Ingred Name:D-GLUCOSE; ((+)-GLUCOSE; (A-D(+)-GLUCOSE ANHYDROUS CELL
    CULTURE TESTED)
CAS:50-99-7
RTECS #:LZ6600000
= Wt:100.

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL, RAT) 25800 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMUFL BY  INHALATION,
    INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION.
Effects of Overexposure:SEE HEALTH HAZARDS.

=======================  First Aid Measures  =======================

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IN CASE OF CONTACT,
    IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF  WATER. IF
    INHALED, REMOVE  TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICAIL
    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED,
    WSH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A
    PHYSICIAN. WASH CONTAMIN ATED CLOTHING BEFORE REUSE.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
    APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APRPOVED SELF-CONTAINED BREATHING
    APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND
    EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:CHEMICAL SAFETY GOGGLES. USE PROTECTIVE
    CLOTHING, GLOVES AND MASK. SWEEP UP, PLACE IN A BAG AND HOLD FOR
    WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL
    SITE AFTER MATERIAL PICKUP IS  COMPLETE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
    EYES, ON SKIN, ON CLOTHING. WASH THOROUGHLY AFTER HANDLING.
Other Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH APPROVED RESPIRATOR IN NONVENTILATED AREAS
    AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: CELL CULTURE TESTED. WASTE DISP METH:
    SUITABILITY OF METHOD USE LICENSED WASTE DISP COMPANY. OBSERVE ALL
    FEDERAL, STATE & LOCAL ENVIRONMENTAL REGS. TOX INFO: (RTECS) DATA
    IS PR ESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFO.

==================  Physical/Chemical Properties  ==================

Appearance and Odor:SOLID.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
    CARBON DIOXIDE.

===================  Toxicological Information	===================

Toxicological Information:RTECS #: LZ6600000. D-GLUCOSE. TOX DATA:
    ORL-RAT LD50:25800 MG/KG. 85AIAL -,39, 1973. IPR-MUS LD50:18 GM/KG.
    PSEBAA 35,98,1936. IVN-MUS LD50:9 GM/KG. ARZNAD 18,666, 1968.
    TARGET ORGAN DATA: MATERIAL E FTS (OTHER EFTS ON FEMALE). EFTS OF
    FERTILITY (POST-IMPLANTATION MORTALITY) EFTS ON EMBRYO/FESTUS
    (OTHER EFTS TO EMBYRO/FETUS). SPECIFIC DEVELOPMENTS ABNORM:
    (CRANIOFACIAL), (HEPATOBILIARY SYS), (UROG ENITAL SYS), (OTHER
    DEVELOPMENTAL ABNORMALITIES). EFTS ON NEWBORN: (BIOCHEMICAL &
    METABOLIC), (BEHAVIORAL). ONLY SELECTED REGISTRY TO TOXIC EFTS OF
    CHEM SUBSTANCES (SUPDAT)

=====================  Ecological Information  =====================

Ecological:DATA NOT YET AVAILABLE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISSOLVE IN WATER & DILUTE TO 5% SOLN. CHECK PH
    & ADJUST IT TO 7 IF NEC. POUR SOLN DOWN DRAIN W/RUNNING WATER &
    CONTINUE TO FLUSH DRAIN SYS FOR 10 MINS, PROVIDED THAT RULES @ YOUR
    PLACE OF EMPLOYMENT/ LOC, STATE & FED GUIDELINES ALLOW YOU TO DO
    SO. IF YOU ARE UNABLE TO FLUSH SOLN DOWN DRAIN/IN DOUBT  ABOUT
    (SUPDAT)

===================  MSDS Transport Information  ===================

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
    INFORMATION.

=====================  Regulatory Information  =====================

SARA Title III Information:N//P
Federal Regulatory Information:REVIEWS, STANDARDS AND REGULATIONS:
    OEL=MAK. NOHS 1974: HZD 81836; NIS 117; TNF 16738; NOS 90; TNE
    13670. NOES 1983: HZD 81836; NIS 86; TNF 11017; NOS 102; TNE
    363666; TFE 186490. EPA GENETOX PROGRAM  1988, NEGATIVE: SPERM
    MORPHOLOGY-MOUSE. EPA GENETOX PROGRAM 1988, INCONCLUSIVE: MAMMALIAN
    MICRONUCLEUS. EPA TSCA SECTION 8(B) CHEMICAL INVENTORY. EPA TSCA
    SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIE S. EPA TSCA TEST
    SUBMISSION (TSCATS) DATA BASE, JUNE 1998.

=======================  Other Information  =======================

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