FISHER SCIENTIFIC -- POTASSIUM PERIODATE, P277 -- 6810-00N015228
===================== Product Identification ===================== Product ID:POTASSIUM PERIODATE, P277 MSDS Date:06/30/1994 FSC:6810 NIIN:00N015228 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SPILL PROC: OTHER ABSORB MATL & PLACE INTO CONTRS FOR LATER DISP. FOR LARGER SPILLS, DIKE FAR AHEAD OF SPILL (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: FOR LATER DISP. KEEP UNNEC PEOPLE AWAY. ISOLATE HAZ AREA & DENY ENTRY. AVOID CONTAMINATION OF WATER SOURCES. RTECS #:9999999ZZ Ingred Name:RESP PROT: BE BASED ON SPECIFIC OPERATION, MUST NOT EXCEED WORKING LIMS OF RESP & MUST BE APPRVD BY NIOSH. (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: ANY DUST & MIST RESP. ANY AIR-PURIFYING RESP W/HIGH-EFFICIENCY PARTICULATE FILTER. ANY POWERED AIR- (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: PURIFYING RESP W/DUST & MIST FILTER. ANY POWERED AIR-PURIFYING RESP W/HIGH EFFICIENCY-PARTICULATE. (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: ANY TYPE 'C' SUPP-AIR RESP OPERATED IN PRESS-DEMAND/OTHER POS PRESS/CONTINUOUS-FLOW MODE. ANY SCBA. (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: FOR FIREFIGHTING & OTHER IMMED DANGEROUS TO LIFE/HLTH CNDTNS: ANY SCBA THAT HAS FULL FACEPIECE & IS (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: OPERATED IN PRESS-DEMAND/OTHER POS PRESS MODE. ANY SUPP-AIR RESP THAT HAS FULL FACEPIECE & IS OPERATED (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: IN PRESS-DEMAND/OTHER POS PRESS MODE IN COMBINATION W/AN AUXILIARY SCBA OPERATED IN PRESS-DEMAND OR (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: OTHER POSITIVE-PRESSURE MODE. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP: TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WITH THIS SUBSTANCE. RTECS #:9999999ZZ Ingred Name:EXPLO HAZ: COMBUST MATTER. CONT W/EASILY OXIDIZABLE, ORG/OTHER COMBUST MATLS MAY RSLT IN IGNIT, VIOLENT COMBUST/EXPLO. RTECS #:9999999ZZ Ingred Name:POTASSIUM META-PERIODATE; (POTASSIUM PERIODATE) CAS:7790-21-8 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: GUIDEBOOK, RSPA P 5800.6, GUIDE PAGE 35). FLOOD W/WATER. COOL CONTRS W/FLOODING AMTS OF WATER FROM AS (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: FAR A DIST AS POSS. AVOID BREATHING VAPORS/DUSTS. EVACUATE TO A RADIUS OF 2500 FEET FOR UNCONTROLLABLE FIRES. RTECS #:9999999ZZ Ingred Name:MATLS TO AVOID: (POWDERED): FIRE & EXPLO HAZ. OXIDIZERS: COMBUST MATLS/ORG MATLS: MAY INCR BURNING RATE/CAUSE (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: IGNIT ON CONT; FINELY DIVIDED MATLS MAY RSLT IN EXPLO. REDUCING MATLS: FIRE & EXPLO HAZ. RTECS #:9999999ZZ Other REC Limits:NONE RECOMMENDED Ingred Name:FIRST AID PROC: UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: INGEST: IF VOMIT OCCURS, KEEP HEAD LOWER THAN HIPS TO HELP PVNT ASPIR. TREAT SYMPTOMATICALLY & (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: SUPPORTIVELY. GET MED ATTN IF NEEDED. ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION/SKIN/EYES: MAY CAUSE IRRITATION. CHRONIC: SKIN: REPEATED OR PROLONGED EXPOSURE IRRITANTS MAY CAUSE DERMATITIS. EYES: REPEATED OR PROLONGED CONTACT WITH IRRITANTS MAY CAUSE CONJUNCTIV ITIS. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. PERFORM ARTF RESP IF NEC. KEEP PERS WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH W/SOAP/MILD DETERGENT & LGE AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. EYES: WASH IMMED W/LGE AMTS OF WATER/NORM SALINE, OCCAS LIFTING (ING 6) ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER ONLY, NO DRY CHEM, CARBON DIOXIDE/HALON. FOR LARGER FIRES, FLOOD AREA W/WATER FROM DIST (1993 EMERGENCY (SUP DAT) Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE CONTR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. APPLY COOLING WATER TO SIDES OF CONTRS EXPOSED (SUP DAT) Unusual Fire/Explosion Hazard:NEGLIG FIRE HAZ WHEN EXPOSED TO HEAT/FLAME. OXIDIZER: OXIDIZERS DECOMPOSE, ESP WHEN HEATED, TO YIELD OXYGEN/OTHER GASES WHICH WILL INCR BURNING RATE OF (ING 20) ================== Accidental Release Measures ================== Spill Release Procedures:KEEP COMBUSTS (WOOD, PAPER, OIL, ETC) AWAY FROM SPILLED MATL. DO NOT TOUCH SPILLED MATL. FOR SML DRY SPILLS, W/CLEAN SHOVEL PLACE MATL INTO CLEAN, DRY CONTR & COVER; MOVE CONTRS FROM SPILL AREA. FOR S ML LIQ SPILLS, TAKE UP W/SAND, EARTH OR (ING 9) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. STORE AT ROOM TEMPERATURE IN A TIGHTLY CLOSED CONTAINER. Other Precautions:CONSULT NFPA PUBLICATION 43A, STORAGE OF LIQUID AND SOLID OXIDIZING MATERIALS, FOR STORAGE REQUIREMENTS. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE FOLLOWING RESPS ARE REC BASED ON INFO FOUND IN PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. THEY ARE RANKED IN ORDER FROM MIN TO MAX RESP PROT. THE SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVEL S FOUND IN WORK PLACE, MUST (ING 11) Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . EMPLOYEE MUST WEAR APPROP PROT (IMPERVIOUS) CLTHG & EQUIP (ING 19) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MP: 1080F,582C (DECOMPOSES). PH: 4.9-5.3 (5% SOLN). FIRE FIGHT MEDIA: RESPONSE GUIDEBOOK, RSPA P 5800.6). FIRE FIGHT PROC: TO FLAMES UNTIL WELL AFTER FIRE IS OUT. FOR MASSIVE FIRE IN CARGO AREA, USE U NMANNED HOSE HOLDER/MONITOR NOZZ; IF THIS IS IMPOSS, WITHDRAW FROM AREA & LET FIRE BURN (1993 EMER RESPONSE (ING 2) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:SUP DAT Vapor Density:7.90 Spec Gravity:3.618 pH:SUPDAT Solubility in Water:SLIGHTLY SOLUBLE Appearance and Odor:COLORLESS TO WHITE, TETRAGONAL POWDER OR CRYSTALS Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AMMONIUM PERCHLORATE: IMPACT SENSITIVITY MAY BE GREATLY INCREASED BY CO-CRYSTALLATION. FLAMM MATLS/METALS (ING 4) Stability Condition to Avoid:EXPLODES AT ELEVATED TEMPS. AVOID CONT W/COMBUST MATLS (WOOD, PAPER, FUEL, OIL, ETC); IGNIT/EXPLO MAY RSLT. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE FUMES OF IODINE AND OXIDES OF POTASSIUM. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W STANDARDS, APPLICABLE TO GENERATORS OF HAZ WASTE, 40 CFR 262. EPA HAZARDOUS WASTE NUMBER D001. 100 POUND CERCLA SECTION 103 REPORTABLE QUANTITY. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.