BIO-RAD LABORATORIES -- ANION EXCHANGE RESIN, MSZ-1 -- -
===================== Product Identification ===================== Product ID:ANION EXCHANGE RESIN, MSZ-1 MSDS Date:09/18/1990 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:BIO-RAD LABORATORIES Address:3300 REGATTA BLVD City:RICHMOND State:CA ZIP:94804 Country:US Info Phone Num:415-232-7000 Emergency Phone Num:415-232-7000 Resp. Party Other MSDS Num.:140-1231 Preparer's Name:ROY WOOD CAGE:10987 === Contractor Identification === Company Name:BIO-RAD LABORATORIES Address:3300 REGATTA BLVD Box:City:RICHMOND State:CA ZIP:94804 Country:US Phone:415-232-7000 CAGE:10987 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE, DIETHENYL-, POLYMER WITH AR-ETHENYL-N,N,N-TRIMETHYLBENZENEMETHANAMINIUM CHLORIDE; (TRIMETHYL AMINE FUNCTIONALIZED, CHLORMETHYLATED COPOLYMER OF STYRENE & DIVINYLBENZENE IN THE CHLORIDE FORM) CAS:60177-39-1 Minumum % Wt:20. Maxumum % Wt:80. ===================== Hazards Identification ===================== LD50 LC50 Mixture:HAS NOT BEEN DETERMINED. Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: NO SPECIFIC EFFECTS. SEE EFFECTS OF OVEREXPOSURE. CHRONIC: NO SPECIFIC DATA AVAILABLE, HOWEVER, REPEATED EXPOSURES ARE NOT ANTICIPATED TO CAUSE ANY SIGNIFICANT ADVERSE EFFECTS. Effects of Overexposure:INHALATION: VAPORS ARE UNLIKELY DUE TO PHYSICAL PROPERTIES. CONTACT WITH SKIN OR EYES: SOLID OR DUST MAY CAUSE IRRITATION OR CORNEAL INJURY DUE TO MECHANICAL ACTION. ABSORBED THROUGH SKIN: NOT ABSORBE D THROUGH SKIN DUE TO PHYSICAL PROPERTIES. INGESTION: LOW SINGLE DOSE AND REPEATED DOSE ORAL TOXICITY; USUALLY CONSIDERED TO PASS THROUGH GUT WITHOUT ABSORPTION. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, LIFTING THE UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION. SKIN: WASH OFF IN SOAP AND FLOWING WATER. INHALATION: REMOVE TO FR ESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. CONSULT MEDICAL PERSONNEL. INGESTION: DRINK WATER. MATERIAL WILL PASS THROUGH BODY NORMALLY. NO EFFECT EXPECTED. ===================== Fire Fighting Measures ===================== Autoignition Temp:>500.C, 932.F Extinguishing Media:DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . POSSIBLE FIRE COMBUSTION PRODUCTS: ALKYBENZENES, VINYLBENZENES, NAPHTHALENE, BENZALDEHYDES, PHENOL, CARBON DIOXIDE, WATER, OR GANIC AMINES, CHLORINE, NITROGEN OXIDES, AMMONIA, METHYL CHLORIDE. Unusual Fire/Explosion Hazard:PRODUCT IS NOT COMBUSTIBLE UNTIL MOISTURE IS REMOVED, THEN RESIN STARTS TO BURN IN FLAME AT 230C. AUTOIGNITION OCCURS ABOVE 500C. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP. CAUTION: MAY BE SLIPPERY. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIAL. AN EYE WASH SHOULD BE NEARBY AND READY FOR USE. Other Precautions:PROTECTIVE MEASURES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: PROTECTIVE CLOTHING AND APPROPRIATE RESPIRATORY PROTECTION SHOULD BE WORN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED. IF DUSTS GENERATED, USE NIOSH APPROVED DUST RESPIRATOR. Ventilation:GOOD ROOM VENTILATION USUALLY ADEQUATE FOR MOST OPERATIONS. Protective Gloves:CHEMICAL RESISTANCE GLOVES SUCH AS NEOPRENE. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR LAB COAT OR APRON. Work Hygienic Practices:USE GOOD LABORATORY PRACTICES. WASH HANDS AFTER USING AND BEFORE EATING. DO NOT EAT, DRINK, OR SMOKE IN THE WORK AREA. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:44 LB/FT*3 (H*20 = 1) Solubility in Water:INSOLUBLE. Appearance and Odor:WHITE TO AMBER SOLID (BEADS). ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NITRIC ACID AND OTHER STRONG OXIDIZING AGENTS CAN CAUSE EXPLOSIVE REACTIONS WHEN MIXED WITH ORGANIC MATERIALS SUCH AS ION EXCHANGE RESINS. BEFORE USING STRONG OXIDIZING AGENTS, CONSULT SOURCES KNOWLEDGEABLE IN HANDLING SUCH Stability Condition to Avoid:PROLONGED EXPOSURE TO OXIDIZING AGENTS. Hazardous Decomposition Products:ALKYLBENZENES, VINYLBENZENES, NAPHTHALENE, BENZALDEHYDES, PHENOL, CARBON DIOXIDE, WATER, ORGANIC AMINES, CHLORINE, NITROGEN OXIDES, AMMONIA, METHYL CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:SALVAGE IF POSSIBLE, OTHERWISE COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS ON SPILL REPORTING, WASTE HANDLING, AND WASTE DISPOSAL. ===================== Regulatory Information ===================== State Regulatory Information: ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.