ALDRICH CHEMICAL CO -- CHLOROTRIMETHYLSILANE 98% C7285-4 -- 6810-00N014213
===================== Product Identification ===================== Product ID:CHLOROTRIMETHYLSILANE 98% C7285-4 MSDS Date:03/14/1990 FSC:6810 NIIN:00N014213 === Responsible Party === Company Name:ALDRICH CHEMICAL CO Box:355 City:MILWAUKEE State:WI ZIP:53201 Country:US Info Phone Num:414-273-3850 CAGE:60928 === Contractor Identification === Company Name:ALDRICH CHEMICAL CO INC Address:1001 WEST ST PAUL AVE Box:355 City:MILWAUKEE State:WI ZIP:53233 Country:US Phone:414-273-3850 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:TRIMETHYLCHLOROSILANE (SARA III) CAS:75-77-4 RTECS #:VV2710000 Fraction by Wt: 98% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:HARMFUL IF INGESTED, INHALED, ABSORBED THROUGH SKIN. MATL IS EXTREMELY DESTRUCTIVE TO TISS OF MUC MEMB/UPPER RESP TRACT, EYES, SKIN. INHAL MAY BE FATAL AS RESULT OF SPASM, INFLAMMATION & EDEMA O F LARYNX & BRONCHI, CHEM PNEUMONITIS & PULMONARY EDEMA. CHRONIC: POSSIBLE CARCINOGEN (MFR). Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:IMMEDIATELY FLUSH W/COPIOUS MATS OF WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTF RESP) CALL MD. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-18F,-28C Lower Limits:6.4% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES. FLAMMABLE LIQUID. Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION & FLASH BACK. WATER HYDROLYZES MATL LIBERATING ACIDIC GAS WHICH IN CNTCT W/METAL (SEE SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNITION. WEAR NIOSH/MSHA APPRVD SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER W/DRY-LIME, SAND, OR SODA ASH. PLACE IN COVERED CNTNRS USING NON- SPARKING TOOLS & TRANSPORT OUTDOORS. VENT AREA & (SEESUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. HANDLE/STORE UNDER NITROGEN. KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. KEEP TIGHTLY CLOSED. DO NOT BREATHE VAPOR. Other Precautions:TOXIC. CORROSIVE. POSS CARC. DO NOT GET IN EYES, ON SKIN, CLOTHING. AVOID PRLNGD/RPTD EXPOS. REACTS VIOLENTLY W/WATER. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF ARC WELDING, OPEN FLAMES, H OT SURFS. HEAT &/OR UV (SEE SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE ONLY IN CHEMICAL FUME HOOD. Protective Gloves:CHEMICAL RESISTANT GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES . Supplemental Safety and Health EXPLO HAZ:SURFS CAN GENERATE FLAMM &/OR EXPLO HYDROGEN GAS. EMITS TOXIC FUMES/CNTNR EXPLO MAY OCCUR UNDER FIRE CNDTNS. THERMAL DECOMP PRODS MAY INCLUDE HCL & PHOSGENE . SPILL PROC: WASH SPILL SI TE AFTER MATL PICKUP COMPLETE. OTHER PREC:RADIATION MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE . ================== Physical/Chemical Properties ================== HCC:F6 Boiling Pt:B.P. Text:135F,57C Melt/Freeze Pt:M.P/F.P Text:-40F,-40C Vapor Pres:100 @ 25C Vapor Density:3.7 Spec Gravity:0.856 Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG BASES, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:DO NOT ALLOW CONTACT W/WATER. Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON DIOXIDE, SILICON OXIDE, HYDROGEN CHLORIDE GAS. PHOSGENE . ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN CHEMICAL INCINERATOR EQUIPPED W/ AFTERBURNER & SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS MATERIAL IS HIGHLY FLAMMABLE. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.