SIGMA CHEMICAL COMPANY -- SODIUM MOLYBDATE DIHYDRATE ACS REAGENT S664 -- 6810-00-764-2235
===================== Product Identification ===================== Product ID:SODIUM MOLYBDATE DIHYDRATE ACS REAGENT S664 MSDS Date:06/02/1992 FSC:6810 NIIN:00-764-2235 === Responsible Party === Company Name:SIGMA CHEMICAL COMPANY Box:14508 City:ST. LOUIS State:MO ZIP:63178 Country:US Info Phone Num:800-325-8070 Emergency Phone Num:314-771-5765 CAGE:21076 === Contractor Identification === Company Name:SIGMA CHEMICAL COMPANY Address:3050 SPRUCE ST Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Phone:314-771-5765 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:MOLYBDIC ACID DISODIUM SALT, DIHYDRATE CAS:10102-40-6 RTECS #:QA5085000 Fraction by Wt: <100% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 (MO) ACGIH TLV:5 MG/M3 (MO) ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 520 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE- MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. CAUSES EYE/SKIN/MUCOUS MEMBRANE & UPPER RESPIRATORY TRACT IRRITATION. CHRONIC-NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALATION: COUGHING, WHEEZING, SHORTNESS OF BREATH. EYES: REDNESS, TEARING, ITCHING. SKIN: REDNESS, RASH, ITCHING. INGESTION: NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES,HOLDING LIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN:WASH WITH SOAP & WATER. INHALATION:REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEEDED. INGESTIO N: IF CONSCIOUS, WASH MOUTH WITH WATER.GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. VENTILATE AREA. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. Neutralizing Agent:SULFURIC ACID AND SODIUM BISULFITE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP TIGHTLY CLOSED. Other Precautions:HARMFUL SOLID. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. DO NOT BREATHE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR SELF CONTAINED BREATHING APPARATUS OR USE NIOSH/MSHA APPROVED RESPIRATOR IF NEEDED. Ventilation:USE ADEQUATE MECHANICAL VENTILATION. Protective Gloves:NEOPRENE Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:3.280 Appearance and Odor:WHITE CRYSTALS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES ==================== Disposal Considerations ==================== Waste Disposal Methods:CAUTIOUSLY ACIDIFY A 3% SOLUTION OF THE MATERIAL TO A PH 2 WITH SULFURIC ACID. GRADUALLY ADD A 50% EXCESS OF AQUEOUS SODIUM BISULFITE. ADJUST PH TO 7 & TREAT WITH SULFIDE TO PRECIPITATE. DISPOSE OF IN CONFORMITY WITH LOCAL, STATE AND FEDERAL LAWS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.