ALDRICH CHEMICAL CO -- DICHLORODIMETHYLSILANE, 99% D6082-6 -- 6810-00N014264
===================== Product Identification ===================== Product ID:DICHLORODIMETHYLSILANE, 99% D6082-6 MSDS Date:05/18/1989 FSC:6810 NIIN:00N014264 === Responsible Party === Company Name:ALDRICH CHEMICAL CO Box:355 City:MILWAUKEE State:WI ZIP:53201 Country:US Info Phone Num:414-273-3850 CAGE:60928 === Contractor Identification === Company Name:ALDRICH CHEMICAL CO INC Address:1001 WEST ST PAUL AVE Box:355 City:MILWAUKEE State:WI ZIP:53233 Country:US Phone:414-273-3850 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:DIMETHYLDICHLOROSILANE (SARA III) CAS:75-78-5 RTECS #:VV3150000 Fraction by Wt: 99% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50:(IHL/RAT)=930PPM,(IHL/MUS)=300MG/M3 Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT, EYES & SKIN. INHALATION MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION & EDEMA OF THE LARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY EDEMA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING THE EYELIDS WITH FINGERS. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. WASH CONTAMINATED CLOTHING BEFORE REUSE. INGEST: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:3F,-16C Lower Limits:5.5% Upper Limits:10.4% Extinguishing Media:CO*2, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES. EXTREMELY FLAMMABLE. Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODUCTS MAY INCLUDE HCL & PHOSGENE . VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO IGNIT SOURCE & FLASH BACK. WATER HYDROLYZES (SEE SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:EVAC AREA. SHUT OFF ALL IGNIT SOURCES. WEAR NIOSH/MSHA APPRVD SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON SAND/VERMICULITE & PLACE IN CLOSED CNTNRS FOR DISP. USE NON-SPARKING TOOLS. VENT AREA & WASH SPILL SITE AFTER MATL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPOR. KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME. DO NOT ALLOW CNTCT WITH WATER. STORE UNDER NITROGEN. REFRIGERATE. Other Precautions:TOXIC, CORROSIVE, LACHRYMATOR. DO NOT GET IN EYES, ON SKIN OR CLOTHING. NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENL VICINITY OF ARC WELDING, OPEN FLAME, HOT SURFACES. HEAT AND/OR UV RADIATION MA Y CAUSE FORM OF HCL & PHOSGENE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves:CHEMICAL-RESISTANT GLOVES Eye Protection:CHEM WORK GOGGLES/FACESHLD OPTNL Other Protective Equipment:RUBBER BOOTS AND OTHER PROTECTIVE EQUIPMENT, SAFETY SHOWER AND EYE BATH Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES . Supplemental Safety and Health EXPLO HAZ: MATERIAL LIBERATING ACIDIC GAS WHICH IN CONTACT WITH METAL SURFACES CAN GENERATE FLAMMABLE AND/OR EXPLOSIVE HYDROGEN GAS. ================== Physical/Chemical Properties ================== HCC:F5 Boiling Pt:B.P. Text:158F,70C Melt/Freeze Pt:M.P/F.P Text:-105F,-76C Vapor Pres:135 @ 25C Vapor Density:1.45 Spec Gravity:1.064 Appearance and Odor:COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ALCOHOLS, AMINES, STRONG BASES, REACTS VIOLENTLY WITH WATER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF: CO, CO*2, SIO*X. HCL AND PHOSGENE . ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. DISPOSE I/A/W FEDERAL, STATE AND LOCAL LAWS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.