SIGMA CHEMICAL COMPANY -- CONGO RED CERTIFIED,C 6277 -- 6550-01-267-5524
===================== Product Identification ===================== Product ID:CONGO RED CERTIFIED,C 6277 MSDS Date:10/11/1989 FSC:6550 NIIN:01-267-5524 === Responsible Party === Company Name:SIGMA CHEMICAL COMPANY Box:14508 City:ST. LOUIS State:MO ZIP:63178 Info Phone Num:800-325-8070 Emergency Phone Num:314-771-5765 CAGE:21076 === Contractor Identification === Company Name:SIGMA CHEMICAL COMPANY Address:3050 SPRUCE ST Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Phone:314-771-5765 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:1-NAPHTHALENESULFONIC ACID, 3,3'-(4,4'-BIPHENYLENEBIS(AZO))BIS(4-AMINO-), DISODIUM SALT CAS:573-58-0 RTECS #:QK1400000 Other REC Limits:NONE SPECIFIED OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE- HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. ORAL LDL0 IN MAN IS 143 MG/KG. MAY CAUSE EYE, SKIN, RESPIRATORY TRACT IRRITATION. CHRONIC- PULMONARY EDEMA OR CONGESTION. THE CHEMICAL, P HYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. Effects of Overexposure:HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. MAY CAUSE EYE, SKIN OR RESPIRATORY TRACT IRRITATION. THE CHEMICAL, PHYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.EYE/SKIN:FLUSH WITH WATER FOR 15 MINUTES.HOLD EYELIDS OPEN.INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.ORAL:FLUSH OUT MOUTH WITH WATER.SEEK MED ICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CO2, WATER SPRAY, ALCOHOL OR POLYMER FOAM OR DRY CHEMICAL POWDER. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED CONTAINER Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:TOXIC FUMES ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND GLOVES. ABSORB ON SAND, VERMICULITE, SAWDUST AND PUT IN A CONTAINER FOR FUTURE DISPOSAL. WASH AND VENTILATE SPILL SITE AFTER PICKUP IS COMPLET E. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE IN A COOL,DRY PLACE.KEEP TIGHTLY CLOSED. Other Precautions:DO NOT RAISE DUST. AVOID CONTACT WITH EYES AND SKIN. AVOID BREATHING DUST. WASH THOROUGHLY AFTER HANDLING MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ONLY IN A CHEMICAL FUME HOOD OR WEAR A NIOSH/MSHA APPROVED SELF CONTAINED BREATHING APPARATUS. Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:RUBBER Eye Protection:DUST-RESISTANT SAFETY GOGGLES Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER, APPROPRIATE LABORATORY COAT TO COVER EXPOSED SKIN Work Hygienic Practices:TOXIC. DO NOT PERMIT EATING, DRINKING OR SMOKING NEAR THIS MATERIAL. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:BROWN-RED POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:FLAMES Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON DIOXIDE AND SULFUR OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.