FISHER SCIENTIFIC -- ACETIC ACID, GLACIAL, A38FP 500 -- 6810-00N076715
===================== Product Identification ===================== Product ID:ACETIC ACID, GLACIAL, A38FP 500 MSDS Date:03/04/1996 FSC:6810 NIIN:00N076715 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (CERCLA) LD50 (ORAL RAT): 3310 MG/KG CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 97% OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT: ISOCYANATE, PHOSPHORUS TRICHLORIDE, POTASSIUM HYDROXIDE, POTASSIUM-T-BUTOXIDE, SODIUM HYDROXIDE, (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: SODIUM PEROXIDE, AND XYLENE. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ Ingred Name:OTHER PREC: INCOMPATIBLE SUBSTANCES. STORE IN SUITABLE CONTR IN DRY AREA ABOVE SUBSTANCE'S FREEZING POINT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: SEV IRRIT. CONT W/LIQ/VAP CAUSES SEV BURNS & POSS IRREVERSIBLE EYE DMG. SKIN: SEV IRRIT. MAY CAUSE SKIN SENSIT, AN ALLERGIC RXN, WHICH BECOMES EVIDENT UPON RE-EXPOS TO THIS MATL. INGEST: M AY CAUSE SEV & PERM DMG TO DIGESTIVE TRACT. CAUSES SEV PAIN, NAUS, VOMIT, DIARR, & SHOCK. (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: INHAL: EFTS MAY BE DELAYED. CAUSES RESP TRACT IRRIT. CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DERM. RPTD INHAL MAY CAUSE CHRONIC BRONCHITIS. RPTD EXPOS MAY CAUSE EROSION OF TEETH. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: GET MED AID IMMED. IMMED FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN WHILE REM OVING CONTAM CLTHG & SHOES. INGEST: DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. GET MED AID IMMED. (ING 4) ===================== Fire Fighting Measures ===================== Flash Point:103F,39C Lower Limits:5.4% Upper Limits:16% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:REACTS WITH MOST METALS TO FORM HIGHLY FLAMMABLE HYDROGEN GAS WHICH CAN FORM EXPLOSIVE MIXTURES WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILL W/INERT MATL (E.G., DRY SAND/EARTH), THEN PLACE INTO CHEM WASTE CONTR. USE WATER SPRAY TO DILUTE SPILL TO A NON-FLAMM MIX. AVOID RUNOFF INTO STORM SEWERS & DITCHES WHICH LEAD TO WATERWAYS . REMOVE ALL SOURCES OF IGNITION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQ VENT. EMPTY CONTRS RETAIN PROD RESIDUE (LIQ &/VAP), & CAN BE DANGEROUS. DO NOT GET ON SKIN/IN EYES. AVOID INGEST & INHALATION. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE SUCH CONTRS TO HEAT, SPKS/OPEN FLAMES. AVOID CONT W/HEAT, SPKS & FLAME. KEEP AWAY FROM HEAT, SPKS, & FLAME. STORE IN COOL, DRY, WELL-VE NTILATED AREA, AWAY FROM (ING 6) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health PH: 2.4 (1M), 2.9 (0.1M). SOL IN H*2O: SOL; RELEASES HEAT/VAP. MATLS TO AVOID: ACID, CHROMIC ACID, CHROMIC ANHYDRIDE + ACETIC ANHYDRIDE, DIALLYL METHYL CARBINOL + OZONE, ETHYLENE DIAMINE, ETHYLENEIMIN E, HYDROGEN PEROXIDE, NITRIC ACID, NITRIC ACID + ACETONE, OLEUM, PERCHLORIC ACID, PERMANGANATES, PHOSPHORUS (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:244F,118C Melt/Freeze Pt:M.P/F.P Text:62.0F,16.7C Vapor Pres:11.4 Vapor Density:2.10 Spec Gravity:1.05 (H*2O=1) pH:SUPDAT Evaporation Rate & Reference:0.97 (N-BUTYL ACETATE=1) Solubility in Water:SUP DAT Appearance and Odor:COLORLESS LIQUID, PUNGENT (VINEGAR) ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETALDEHYDE, 2-AMINOETHANOL, AMMONIUM NITRATE, BROMINE PENTAFLUORIDE, CHLORINE TRIFLUORIDE, CHLOROSULFONIC (SUP DAT) Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES, EXCESS HEAT. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.