FISHER SCIENTIFIC CHEMICAL DIVISION -- NICKEL SULFATE -- 6810-00-237-2909
===================== Product Identification ===================== Product ID:NICKEL SULFATE MSDS Date:10/12/1988 FSC:6810 NIIN:00-237-2909 === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL DIVISION Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7523 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL SULFATE HEXAHYDRATE CAS:10101-97-0 RTECS #:QR9600000 Fraction by Wt: > 99.0% OSHA PEL:0.1 MG/M3 (NI) ACGIH TLV:0.1 MG/M3 (NI); 8990 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 275 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRITATION OF MUCOUS MEMBRANES OF UPPER RESPIRATORY TRACT, SENSITIZATION DERMATITIS, CONJUNCTIVA, REDNESS AND PAIN OF EYES, IRRITATION, VOMITING AND DIARRHEA. CHRONIC: POSSIBLE CANCER OF THE NA SAL PASSAGES AND LUNGS. REVERSIBLE ADVERSE EFFECTS ON MALE REPRODUCTIVE ORGANS. Explanation of Carcinogenicity:NTP & IARC INDICATE SUFFICIENT EVIDENCE OF NICKEL AND CERTAIN NICKEL COMPOUNDS TO BE SUSPECTED CARCINOGENS. Effects of Overexposure:SEE HEALTH HAZARDS DATA Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION: INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE CARBON DIOXIDE, HALON, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. DO NOT SCATTER SPILLED MATERIAL WITH HIGH PRESSURE WATER STREAMS. DIKE FORE CONTROL WATER FOR LATER DISPOSAL. Unusual Fire/Explosion Hazard:USE AGENTS SUITABLE FOR TYPE OF SURROUNDING FIRE. ABOID BREATHING HAZARDOUS VAPORS OR DUSTS, KEEP UPWIND. ================== Accidental Release Measures ================== Spill Release Procedures:SOIL SPILL: DIG HOLDING AREA AND COVER TO PREVENT DISSOLVING. WATER SPILL: NEUTRALIZE WITH CAUSTIC SODA. OCCUPATIONAL SPILL: STOP LEAK W/OUT RISK. TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL AND PLA CE INTO CLEAN, DRY CONTINER. ISOLATE HAZARD AREA! Neutralizing Agent:CAUSTIC SODA. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:DO NOT TAKE INTERNALLY. AVOID PROLONGED OR REPEATED BREATHING OF DUST. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED. Protective Gloves:NEOPRENE, NITRILE, VPC OR NATURAL RUBBER Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT WEAR CONTACT LENSES. ================== Physical/Chemical Properties ================== HCC:C3 Boiling Pt:B.P. Text:217F,103C Melt/Freeze Pt:M.P/F.P Text:128F,53C Vapor Pres:0.0 Spec Gravity:2.07 pH:4.0 Solubility in Water:40% @ 20C Appearance and Odor:ODORLESS, BLUE OR EMERALD GREEN, EFFLORESCENT CRYSTALS W/ SWEET ASTRINGENT TAST ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES. MAY BURN BUT DOES NOT READILY IGNITE. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC AND HAZARDOUS SULFUR OXIDES. Conditions to Avoid Polymerization:ABNORMAL TEMPERATURES AND PRESSURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.