ALDRICH CHEMICAL CO INC -- DIBUTYLAMINE, 99+%, 24000-1  -- 6810-00N065012
<pre>=====================  Product Identification  =====================

Product ID:DIBUTYLAMINE, 99+%, 24000-1
MSDS Date:07/03/1995
FSC:6810
NIIN:00N065012
=== Responsible Party ===
Company Name:ALDRICH CHEMICAL CO INC
Box:355
City:MILWAUKEE
State:WI
ZIP:53201
Country:US
Info Phone Num:414-273-3850
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company Name:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928

=============  Composition/Information on Ingredients  =============

Ingred Name:DIBUTYLAMINE
CAS:111-92-2
RTECS #:HR7780000
Fraction by Wt: >99%
OSHA PEL:N/K 
ACGIH TLV:N/K 

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50(ORAL,RAT):189 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED, INHALED OR
    ABSORBED THROUGH SKIN. CAUSES BURNS. MATERIAL IS EXTREMELY
    DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY
    TRACT, EYES AND SKIN. INHALATION M AY BE FATAL AS RESULT OF SPASM,
    INFLAM & EDEMA OF LARYNX & BRONCHI, CHEM PNEUM & PULM EDEMA. SYMPS
    OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:EXPOS MAY INCLUDE BURNING SENSATION,
    COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BRTH, HDCH, NAUS &
    VOMIT. CHRONIC:LAB EXPER HAVE SHOWN MUTAGENIC EFTS. ADDNL
    INFO:EXPOS TO VAP, EVEN IN LOW  CONCS, CAN CAUSE LACRIMATION,
    CONJUNCT & CORNEAL EDEMA WHEN VAP IS ABSORBED INTO TISS OF EYE.
    CORNEAL EDEMA MAY (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYES:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
    MINUTES. SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
    MINUTES WHILE REMOVING CONTAM CLTHG & SHOES. WASH CONTAM CLTHG
    BEFORE REUSE.  INHAL:REMOVE TO FRESH AIR. IF NOT BRTHGGIVE ARTF
    RESP. IF BRTHG IS DFCLT, GIVE OXYG. INGESTION:WASH OUT MOUTH WITH
    WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN.

=====================  Fire Fighting Measures  =====================

Flash Point:106F,41C
Lower Limits:1.1%
Upper Limits:10%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
    FOAM, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
    PROTECTIVE EQUIPMENT . COMBUSTIBLE.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND
    FLASH BACK.

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA,
    RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE
    AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND
    WASH SPILL SITE AFTER  MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT BREATHE VAPOR. AVOID CONTACT
    WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
    CORROSIVE. TOXIC. POSSIBLE MUTAGEN.
Other Precautions:HARMFUL LIQUID. KEEP TIGHTLY CLOSED. KEEP AWAY FROM
    HEAT AND OPEN FLAME. STORE IN A COOL, DRY PLACE. KEEP AWAY FROM
    SOURCES OF IGNITION. NO SMOKING.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
    SHOWER . OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP:GIVE RISE TO PERCEPTION OF A "HALO", "BLUE HAZE" OR
    "FOG" AROUND LIGHTS. THIS EFFECT IS USUALLY REVERSIBLE ALTHOUGH IT
    MAY LAST A COUPLE OF DAYS.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:318F,159C
Melt/Freeze Pt:M.P/F.P Text:-80F,-62C
Vapor Pres:1.9 @ 20C
Vapor Density:4.46
Spec Gravity:0.767
Appearance and Odor:COLORLESS LIQUID.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ACIDS, ACID CHLORIDES & ANHYDRIDES, STRONG OXIDIZING AGENTS, CARBON
    DIOXIDE, ALUMINUM, ZINC, GALVANIZED IRON, COPPER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
    CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN OXIDES.

====================  Disposal Considerations  ====================

Waste Disposal Methods:THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A
    CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

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